5-{2-(5-imidazolylvaleryloxy)-6-(pivaloyloxy)phenyl}-10,15,20-tris{2,6-bis(pivaloyloxy)phenyl}porphyrinatoiron(II)

Base Information

• Chemical Name: 5-{2-(5-imidazolylvaleryloxy)-6-(pivaloyloxy)phenyl}-10,15,20-tris{2,6-bis(pivaloyloxy)phenyl}porphyrinatoiron(II)
• CAS No.: 151602-81-2
• Molecular Formula: C₈₇H₉₄FeN₆O₁₆
• Molecular Weight: 1535.58
• Mol file: 151602-81-2.mol

Synonyms:

Chemical Property of 5-{2-(5-imidazolylvaleryloxy)-6-(pivaloyloxy)phenyl}-10,15,20-tris{2,6-bis(pivaloyloxy)phenyl}porphyrinatoiron(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5-{2-(5-imidazolylvaleryloxy)-6-(pivaloyloxy)phenyl}-10,15,20-tris{2,6-bis(pivaloyloxy)phenyl}porphyrinatoiron(II)

There total 2 articles about 5-{2-(5-imidazolylvaleryloxy)-6-(pivaloyloxy)phenyl}-10,15,20-tris{2,6-bis(pivaloyloxy)phenyl}porphyrinatoiron(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[5-[2-(5-imidazol-1-ylvaleryloxy)-6-(pivaloyloxy)phenyl]-10,15,20-tris[2,6-bis(pivaloyloxy)phenyl]porphyrinato]iron(III) bromide (151602-80-1) → 5-{2-(5-imidazolylvaleryloxy)-6-(pivaloyloxy)phenyl}-10,15,20-tris{2,6-bis(pivaloyloxy)phenyl}porphyrinatoiron(II) (151602-81-2)

Guidance literature:

With sodium dithionite; In dichloromethane; water; (anaerobic conditions); spectr. monitoring;

DOI:10.1039/a802925c

Reference yield:

{C87H94N6O16FeBr} (151602-80-1) → 5-{2-(5-imidazolylvaleryloxy)-6-(pivaloyloxy)phenyl}-10,15,20-tris{2,6-bis(pivaloyloxy)phenyl}porphyrinatoiron(II) (151602-81-2)

Guidance literature:

With sodium dithionite; In water; toluene; redn. by Na2S2O4 in the two phase system toluene-water under anaerobic conditions;; sepn. of two phases; no isolation of the Fe complex (organic phase); detn. by NMR and IR spectroscopy;;

upstream raw materials:

[5-[2-(5-imidazol-1-ylvaleryloxy)-6-(pivaloyloxy)phenyl]-10,15,20-tris[2,6-bis(pivaloyloxy)phenyl]porphyrinato]iron(III) bromide

{C₈₇H₉₄N₆O₁₆FeBr}