[Na(N,N,N'N'-tetramethylethylenediamine)2(3-Me-C₆H₄CN)2][[6-Zn(tBu)2-3-Me-C₆H₃CN]2Na

Base Information

• Chemical Name: [Na(N,N,N'N'-tetramethylethylenediamine)2(3-Me-C₆H₄CN)2][[6-Zn(tBu)2-3-Me-C₆H₃CN]2Na
• CAS No.: 1010136-55-6
• Molecular Formula: C₂₈H₄₆N₆Na*C₄₄H₈₀N₆NaZn₂
• Molecular Weight: 1336.63
• Mol file: 1010136-55-6.mol

Synonyms:

Chemical Property of [Na(N,N,N'N'-tetramethylethylenediamine)2(3-Me-C₆H₄CN)2][[6-Zn(tBu)2-3-Me-C₆H₃CN]2Na

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Na(N,N,N'N'-tetramethylethylenediamine)2(3-Me-C₆H₄CN)2][[6-Zn(tBu)2-3-Me-C₆H₃CN]2Na

There total 1 articles about [Na(N,N,N'N'-tetramethylethylenediamine)2(3-Me-C₆H₄CN)2][[6-Zn(tBu)2-3-Me-C₆H₃CN]2Na which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 29.3%

2,2,6,6-tetramethyl-piperidine (768-66-1) + N,N,N,N,-tetramethylethylenediamine (110-18-9) + butylsodium (3525-44-8) + di-tert-butylzinc (16636-96-7) + 3-Methylbenzonitrile (620-22-4) → [Na(N,N,N'N'-tetramethylethylenediamine)2(3-Me-C6H4CN)2][[6-Zn(tBu)2-3-Me-C6H3CN]2Na (1010136-55-6)

Guidance literature:

In hexane; Sonication; BuNa suspended in hexane, sonicated 10 min, (CH3)4C5H6NH added; stirred for 1 h, tBu2Zn in hexane and TMEDA added; stirred for 45 min, meta-tolunitrile added; 5 ml of toluene added, crystd. at -24°C;

DOI:10.1002/anie.200704341

upstream raw materials:

2,2,6,6-tetramethyl-piperidine

N,N,N,N,-tetramethylethylenediamine

butylsodium

di-tert-butylzinc