[(P(CH₃)3)Ru(C₉H₇)(P(C₆H₅)3)(OC(C(CH₃)3)CH₂P(C₆H₅)2)]⁽¹⁺⁾*PF₆^(1-)=(P(CH₃)3)Ru(C₉H₇)(P(C₆H₅)3)(OC(C(CH₃)3)CH₂P(C₆H₅)2)PF₆

Base Information

• Chemical Name: [(P(CH₃)3)Ru(C₉H₇)(P(C₆H₅)3)(OC(C(CH₃)3)CH₂P(C₆H₅)2)]⁽¹⁺⁾*PF₆^(1-)=(P(CH₃)3)Ru(C₉H₇)(P(C₆H₅)3)(OC(C(CH₃)3)CH₂P(C₆H₅)2)PF₆
• CAS No.: 916907-60-3
• Molecular Formula: C₄₈H₅₂OP₃Ru*F₆P
• Molecular Weight: 983.896
• Mol file: 916907-60-3.mol

Synonyms:

Chemical Property of [(P(CH₃)3)Ru(C₉H₇)(P(C₆H₅)3)(OC(C(CH₃)3)CH₂P(C₆H₅)2)]⁽¹⁺⁾*PF₆^(1-)=(P(CH₃)3)Ru(C₉H₇)(P(C₆H₅)3)(OC(C(CH₃)3)CH₂P(C₆H₅)2)PF₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(P(CH₃)3)Ru(C₉H₇)(P(C₆H₅)3)(OC(C(CH₃)3)CH₂P(C₆H₅)2)]⁽¹⁺⁾*PF₆^(1-)=(P(CH₃)3)Ru(C₉H₇)(P(C₆H₅)3)(OC(C(CH₃)3)CH₂P(C₆H₅)2)PF₆

There total 1 articles about [(P(CH₃)3)Ru(C₉H₇)(P(C₆H₅)3)(OC(C(CH₃)3)CH₂P(C₆H₅)2)]⁽¹⁺⁾*PF₆^(1-)=(P(CH₃)3)Ru(C₉H₇)(P(C₆H₅)3)(OC(C(CH₃)3)CH₂P(C₆H₅)2)PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

[Ru(η(5)-indenyl)(triphenylphosphine)(η(2)(P,O)-Ph2PCH2C(=O)Bu(t))](PF6) (198897-44-8) + trimethylphosphane (594-09-2) → [(P(CH3)3)Ru(C9H7)(P(C6H5)3)(OC(C(CH3)3)CH2P(C6H5)2)](1+)*PF6(1-)=(P(CH3)3)Ru(C9H7)(P(C6H5)3)(OC(C(CH3)3)CH2P(C6H5)2)PF6 (916907-60-3)

Guidance literature:

In tetrahydrofuran; inert atm., stirred overnight; evapd. to dryness, recrystd. (CH2Cl2/diethyl ether); elem. anal.;

DOI:10.1002/ejic.200501073

Reference yield: 77.0%

hydrogenchloride (7647-01-0,15364-23-5) + ammonium hexafluorophosphate + [(P(CH3)3)Ru(C9H7)(P(C6H5)3)(OC(C(CH3)3)CH2P(C6H5)2)](1+)*PF6(1-)=(P(CH3)3)Ru(C9H7)(P(C6H5)3)(OC(C(CH3)3)CH2P(C6H5)2)PF6 (916907-60-3) → [(P(CH3)3)Ru(C9H7)(OC(C(CH3)3)CH2P(C6H5)2)](1+)*PF6(1-)=[(P(CH3)3)Ru(C9H7)(OC(C(CH3)3)CH2P(C6H5)2)]PF6 (916907-62-5)

Guidance literature:

With NaH; In tetrahydrofuran; inert atm., Ru compd. (methanol) refluxed for 20 h, filtered, evapd. to dryness, methanol added, stirred, a soln. of HCl (diethyl ether) and F compd. added, stirred for 10 min; ppt. filtered, washed (diethyl ether), extd. (CH2Cl2), filtered, covered(methanol/diethyl ether); elem. anal.;

DOI:10.1002/ejic.200501073

upstream raw materials:

[Ru(η(5)-indenyl)(triphenylphosphine)(η(2)(P,O)-Ph2PCH2C(=O)Bu(t))](PF6)

trimethylphosphane

Downstream raw materials:

[(P(CH₃)3)Ru(C₉H₇)(OC(C(CH₃)3)CH₂P(C₆H₅)2)]⁽¹⁺⁾*PF₆^(1-)=[(P(CH₃)3)Ru(C₉H₇)(OC(C(CH₃)3)CH₂P(C₆H₅)2)]PF₆