cis-Pt(Et₃P)Cl(CCPh)

Base Information

Chemical Name:cis-Pt(Et₃P)Cl(CCPh)
CAS No.:15927-87-4
Molecular Formula:C₂₀H₃₅ClP₂Pt
Molecular Weight:567.978
Hs Code.:

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Chemical Property of cis-Pt(Et₃P)Cl(CCPh)

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Technology Process of cis-Pt(Et₃P)Cl(CCPh)

There total 2 articles about cis-Pt(Et₃P)Cl(CCPh) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

: 14177-93-6,15692-07-6,13965-02-1
trans-platinum(triethylphosphine)₂(chloro)₂

: 536-74-3
phenylacetylene

: 15927-87-4,108647-11-6
trans-chloro(phenylethynyl)bis(triethylphosphine)platinum(II)

Guidance literature:: With triethylamine; CuI; In toluene; CuI and NEt3 added to soln. of trans-PtCl2(PEt3)2 in toluene, cooled to 0°C, soln. of phenylacetylene in toluene added, stirred at 0°C for 1 h and then at room temp. for 12 h; filtered, filtrate evapd., residue dissolved in CH2Cl2, treated with NH4Cl soln. and water, org. phase dried over MgSO4 and evapd. to dryness, column chromy. (basic alumina, CH2Cl2/pentane (3/7));
DOI:10.1039/b210252h

Reference yield:

: 14177-93-6,15692-07-6,13965-02-1
trans-platinum(triethylphosphine)₂(chloro)₂

: trans-bis(ethynylbenzene)bis(triethylphosphine)platinum(II)

: 15927-87-4,108647-11-6
trans-chloro(phenylethynyl)bis(triethylphosphine)platinum(II)

Guidance literature:: With (CH₃)3SnCl; In tetrahydrofuran; 5 days, 60°C, addn. of small amount of Me3SnCl to reaction soln.; monitored by 31P-NMR;
DOI:10.1016/0022-328X(86)80237-6

Reference yield: 87.0%

: 15927-87-4,108647-11-6
trans-chloro(phenylethynyl)bis(triethylphosphine)platinum(II)

: 454183-90-5
5,11,17,23-tetraethynyl-25,26,27,28-tetrapropoxythiacalix[4]arene

: 454183-94-9
5,11,17,23-tetra[trans-(phenylethynyl)ethynyl-bis(triethylphosphine)platinum(II)]-25,26,27,28-tetrapropoxythiacalix[4]arene

Guidance literature:: With CuI; triethylamine; In toluene; CuI and NEt3 added to soln. of trans-PtCl(CCPh)(PEt3)2 in toluene, cooled to 0°C, soln. of thiacalixarene in toluene added, stirred at room temp. for 12 h; evapd., residue dissolved in CH2Cl2 and treated with NH4Cl soln. and water, org. phase dried over MgSO4 and evapd. to dryness, column chromy. (basic alumina, CH2Cl2/pentane (2/8));
DOI:10.1039/b210252h