{((CH₃)3CO)3W⁽¹³⁾C}2

Base Information

• Chemical Name: {((CH₃)3CO)3W⁽¹³⁾C}2
• CAS No.: 108919-87-5
• Molecular Formula: C₂₆H₅₄O₆W₂
• Molecular Weight: 832.389
• Mol file: 108919-87-5.mol

Synonyms:

Chemical Property of {((CH₃)3CO)3W⁽¹³⁾C}2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {((CH₃)3CO)3W⁽¹³⁾C}2

There total 3 articles about {((CH₃)3CO)3W⁽¹³⁾C}2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ditungsten hexa-tert-butoxide (57125-20-9) + trans-Pt((13)C2H)2(PMe2Ph)2 → trans-Pt((13)C2H){(13)C2W2(O-t-Bu)5}(PMe2Ph)2 + {((CH3)3CO)3W(13)C}2 (108919-87-5) + trans-Pt{(13)C2W2(O-t-Bu)5}2(PMe2Ph)2

Guidance literature:

In toluene; byproducts: t-BuOH; W-compound:Pt-compound=1:1, 5-6d at 30°C;; monitoring of react. by (1)H-, (13)C- and (31)P-NMR;;

DOI:10.1021/ja00249a018

Reference yield:

ditungsten hexa-tert-butoxide (57125-20-9) + trans-Pt((13)C2H)2(PMe2Ph)2 → {((CH3)3CO)3W(13)C}2 (108919-87-5) + trans-Pt{(13)C2W2(O-t-Bu)5}2(PMe2Ph)2

Guidance literature:

In toluene; 1.24mmol W-compound, 0.62mmol Pt-compound, 5d, 30°C; evapn. to 50% of volume, cooling to -15°C:; separation of ((t-BuO)3WC)2 from main product by crystn. from toluene by slowly cooling; (13)C-NMR;;

DOI:10.1021/ja00249a018

Reference yield:

ditungsten hexa-tert-butoxide (57125-20-9) + trans-Pt((13)C2H)2(PMe2Ph)2 → trans-Pt((13)C(13)CH)[C2W2(O-t-Bu)5](PMe2Ph)2 + {((CH3)3CO)3W(13)C}2 (108919-87-5)

Guidance literature:

In not given; byproducts: (CH3)3COH; under dry oxygen-free N2; monitored by NMR;

DOI:10.1039/c39850001582

upstream raw materials:

ditungsten hexa-tert-butoxide