2-METHOXY-4-NITROPHENOL, POTASSIUM SALT HYDRATE

Base Information

• Chemical Name: 2-METHOXY-4-NITROPHENOL, POTASSIUM SALT HYDRATE
• CAS No.: 100200-99-5
• Molecular Formula: C7H7NO4.K
• Molecular Weight: 207.227
• Mol file: 100200-99-5.mol

Synonyms:potassium 4-nitroguaiacoxide;4-Nitroguajacole Potassium Salt;potassium 2-methoxy-4-nitrophenolate monohydrate;2-methoxy-4-nitrophenol potassium salt;potassium 2-methoxy-4-nitrophenoxide;potassium 2-methoxy-4-nitrophenolate;

Chemical Property of 2-METHOXY-4-NITROPHENOL, POTASSIUM SALT HYDRATE

Chemical Property:

• Melting Point: >300?°C(lit.)
• PSA: 78.11000
• LogP: 2.27040

Purity/Quality:

99% ^*data from raw suppliers

4-Nitroguaiacol potassium salt hydrate 98% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-METHOXY-4-NITROPHENOL, POTASSIUM SALT HYDRATE

There total 1 articles about 2-METHOXY-4-NITROPHENOL, POTASSIUM SALT HYDRATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

3,4-dimethoxynitrobenzene (709-09-1) → potassium 2-methoxy-4-nitrophenolate monohydrate (100200-99-5)

Guidance literature:

With potassium hydroxide; In water; for 9h; Heating;

Reference yield: 98.0%

potassium 2-methoxy-4-nitrophenolate monohydrate (100200-99-5) + (R)-glycidyl nosylate (115314-14-2,115314-17-5) → (R)-2-((2-methoxy-4-nitrophenoxy)methyl)oxirane (394248-96-5)

Guidance literature:

With cesium fluoride; In N,N-dimethyl-formamide; for 48h;

Reference yield: 95.0%

1-bromo-octane (111-83-1) + potassium 2-methoxy-4-nitrophenolate monohydrate (100200-99-5) → 1-Methoxy-5-nitro-2-octyloxybenzene (24019-93-0)

Guidance literature:

With sodium iodide; In N,N-dimethyl-formamide; at 120 ℃;

upstream raw materials:

3,4-dimethoxynitrobenzene

Downstream raw materials:

2-Aethyl-1-(4-nitro-2-methoxy-phenoxy)-hexan

1-(4-Nitro-2-methoxy-phenoxy)-undecan

1,5-bis-(2-methoxy-4-nitro-phenoxy)-pentane

(4-Nitro-2-methoxy-phenoxy)-cyclopentan

Refernces

• 1、 Toeke, Laszlo,Bitter, Istvan,Agai, Bela,Hell, Zoltan,Lindner, Ernoe,et al.. "Benzocrown Derivatives as Ionophores for Alkali Cations, II. - Synthesis and Comparison of Urethane-, Ether-, and Ester-Linked Bis-Crown Compounds and Several "Crown-Ring Free" Analogues". . p. 549 - 554. Retrieved 2007/10/02.