1-(1-adamantyl)-2,2-dimethyl-1-propanone triphenylphosphoranylidenehydrazone

Base Information

• Chemical Name: 1-(1-adamantyl)-2,2-dimethyl-1-propanone triphenylphosphoranylidenehydrazone
• CAS No.: 100083-96-3
• Molecular Formula: C₃₃H₃₉N₂P
• Molecular Weight: 494.66
• Mol file: 100083-96-3.mol

Synonyms:

Chemical Property of 1-(1-adamantyl)-2,2-dimethyl-1-propanone triphenylphosphoranylidenehydrazone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-(1-adamantyl)-2,2-dimethyl-1-propanone triphenylphosphoranylidenehydrazone

There total 3 articles about 1-(1-adamantyl)-2,2-dimethyl-1-propanone triphenylphosphoranylidenehydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-adamantanecarbonitrile (23074-42-2) → 1-(1-adamantyl)-2,2-dimethyl-1-propanone triphenylphosphoranylidenehydrazone (100083-96-3)

Guidance literature:

Multi-step reaction with 3 steps

1: 80 percent / benzene; pentane / 4 h / 25 °C

2: 86 percent / 100percent hydrazine hydrate, 2 N H₂SO₄ / 36 h / Heating

3: 1.) Br₂, 2.) triethylamine / 1.) benzene, room temp., 30 min, 2.) 5 h

With sulfuric acid; bromine; hydrazine hydrate; triethylamine; In pentane; benzene;

Reference yield:

1-(1-adamantyl)-2,2-dimethyl-1-propanimine (100083-94-1,100083-95-2) → 1-(1-adamantyl)-2,2-dimethyl-1-propanone triphenylphosphoranylidenehydrazone (100083-96-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 86 percent / 100percent hydrazine hydrate, 2 N H₂SO₄ / 36 h / Heating

2: 1.) Br₂, 2.) triethylamine / 1.) benzene, room temp., 30 min, 2.) 5 h

With sulfuric acid; bromine; hydrazine hydrate; triethylamine;

Reference yield:

triphenylphosphine (603-35-0) + 1-(1-adamantyl)-2,2-dimethyl-1-propanone hydrazone (89375-83-7) → 1-(1-adamantyl)-2,2-dimethyl-1-propanone triphenylphosphoranylidenehydrazone (100083-96-3)

Guidance literature:

With bromine; triethylamine; Yield given. Multistep reaction; 1.) benzene, room temp., 30 min, 2.) 5 h;

upstream raw materials:

triphenylphosphine

1-(1-adamantyl)-2,2-dimethyl-1-propanone hydrazone

1-adamantanecarbonitrile

1-(1-adamantyl)-2,2-dimethyl-1-propanimine