(meso-5,10,15,20-tetra-p-tolylporphyrinato)Ti=NTMS

Base Information

• Chemical Name: (meso-5,10,15,20-tetra-p-tolylporphyrinato)Ti=NTMS
• CAS No.: 185549-11-5
• Molecular Formula: C₅₁H₄₅N₅SiTi
• Molecular Weight: 803.917
• Mol file: 185549-11-5.mol

Synonyms:

Chemical Property of (meso-5,10,15,20-tetra-p-tolylporphyrinato)Ti=NTMS

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (meso-5,10,15,20-tetra-p-tolylporphyrinato)Ti=NTMS

There total 1 articles about (meso-5,10,15,20-tetra-p-tolylporphyrinato)Ti=NTMS which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

(meso-5,10,15,20-tetra-p-tolylporphyrinato)Ti(η(2)-EtC.tplbond.CEt) (148509-02-8) + trimethylsilylazide (4648-54-8) → (meso-5,10,15,20-tetra-p-tolylporphyrinato)Ti=NTMS (185549-11-5)

Guidance literature:

In toluene; byproducts: N2; N2-atmosphere; excess azide, stirring for 16 h; evapn. (reduced pressure), dissoln. in PhMe, layering with hexanes, crystn. (-20°C, 14 h), collection (filtration), drying (vac.); elem. anal.;

upstream raw materials:

(meso-5,10,15,20-tetra-p-tolylporphyrinato)Ti(η(2)-EtC.tplbond.CEt)

trimethylsilylazide