7-Methoxy-3,5,8,11,13-pentaoxatricyclo[7.4.0.02,6]tridecane

Base Information

Chemical Name:7-Methoxy-3,5,8,11,13-pentaoxatricyclo[7.4.0.02,6]tridecane
CAS No.:23397-81-1
Molecular Formula:C₉H₁₄O₆
Molecular Weight:218.207
Hs Code.:
NSC Number:179669
DSSTox Substance ID:DTXSID60306757

Synonyms:NSC179669;23397-81-1;DTXSID60306757;NSC-179669

Suppliers and Price of 7-Methoxy-3,5,8,11,13-pentaoxatricyclo[7.4.0.02,6]tridecane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 7-Methoxy-3,5,8,11,13-pentaoxatricyclo[7.4.0.02,6]tridecane

Chemical Property:

Vapor Pressure:0.000872mmHg at 25°C
XLogP3:-0.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:1
Exact Mass:218.07903816
Heavy Atom Count:15
Complexity:235

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COC1C2C(C3C(O1)COCO3)OCO2

Technology Process of 7-Methoxy-3,5,8,11,13-pentaoxatricyclo[7.4.0.02,6]tridecane

There total 4 articles about 7-Methoxy-3,5,8,11,13-pentaoxatricyclo[7.4.0.02,6]tridecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 109-87-5
Dimethoxymethane

: 617-04-9
(2R,3S,4S,5S,6S)-2-(hydroxymethyl)-6-methoxytetrahydro-2H-pyran-3,4,5-triol

: 23397-81-1
methyl 2,3:4,6-di-O-methylene-α-D-mannopyranoside

Guidance literature:: With Amberlyst^<*> 15; for 6h; Heating;
DOI:10.1016/0008-6215(95)00218-I

Reference yield: 16.0%

: 67-68-5,8070-53-9
dimethyl sulfoxide

: 617-04-9
(2R,3S,4S,5S,6S)-2-(hydroxymethyl)-6-methoxytetrahydro-2H-pyran-3,4,5-triol

: 23397-81-1
methyl 2,3:4,6-di-O-methylene-α-D-mannopyranoside

: (4aR,6S,6aS,11aS,11bR)-6-Methoxy-hexahydro-1,3,5,7,9,11-hexaoxa-cyclohepta[a]naphthalene

Guidance literature:: With thionyl chloride; at 65 ℃; for 2h;
DOI:10.1016/S0040-4039(97)00882-4

Reference yield:

: 109-87-5
Dimethoxymethane

: 617-04-9
(2R,3S,4S,5S,6S)-2-(hydroxymethyl)-6-methoxytetrahydro-2H-pyran-3,4,5-triol

: 50256-50-3
(4,6-O-methylidene)methyl-α-D-mannopyranoside

: 23397-81-1
methyl 2,3:4,6-di-O-methylene-α-D-mannopyranoside

Guidance literature:: With hydrogenchloride; toluene-4-sulfonic acid; lithium bromide; Yield given. Multistep reaction. Yields of byproduct given; 1a.) dioxan, reflux, 12 h, 1b.) 60 deg C, 1 h, 2.) 50 deg C;