9-methylbenzo[g]chrysene

Base Information

• Chemical Name: 9-methylbenzo[g]chrysene
• CAS No.: 13322-53-7
• Molecular Formula: C₂₃H₁₆
• Molecular Weight: 292.38
• Mol file: 13322-53-7.mol

Synonyms:

Chemical Property of 9-methylbenzo[g]chrysene

Chemical Property:

• Solubility.: DCM, Ethyl Acetate

Purity/Quality:

99% ^*data from raw suppliers

9-Methylbenzo[g]chrysene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Uses: 9-Methylbenzo[g]chrysene is an metabolite of Dibenzo[def,p]chrysene (D416945), an well known polycyclic aromatics hydrocarbons found in hot mix asphalt paving workers and the most potent tumorigen that has been identified to date.

Technology Process of 9-methylbenzo[g]chrysene

There total 3 articles about 9-methylbenzo[g]chrysene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

2-(9-phenanthryl)phenylacetone (1013933-56-6) → 9-methylbenzo[g]chrysene (13322-53-7)

Guidance literature:

With titanium tetrachloride; In dichloromethane; at 20 ℃; for 36h; Time; Temperature; Reagent/catalyst; chemoselective reaction; Reactivity; Inert atmosphere;

DOI:10.1021/ol7029323

Reference yield:

→ 9-methylbenzo[g]chrysene (13322-53-7)

Guidance literature:

With palladium on activated charcoal; at 300 - 350 ℃;

DOI:10.1021/ja01236a019

Reference yield:

9-((Z)-1-Methyl-2-phenyl-vinyl)-phenanthrene → 9-methylbenzo[g]chrysene (13322-53-7)

Guidance literature:

In hexane; Irradiation;

DOI:10.1039/c19660000548

upstream raw materials:

2-(9-phenanthryl)phenylacetone

Refernces

• 1、 Xu, Daiwang,Duan, Yazhen,Blair, Ian A.,Penning, Trevor M.,Harvey, Ronald G.. "Synthesis of dibenzo[def,p]chrysene, its active metabolites, and their 13C-labeled analogues". supporting information; experimental part. p. 1059 - 1062. Retrieved 2009/04/06.