Jasmine lactone

Base Information

Chemical Name:Jasmine lactone
CAS No.:100428-67-9
Deprecated CAS:68170-58-1
Molecular Formula:C₁₀H₁₆O₂
Molecular Weight:168.236
Hs Code.:
European Community (EC) Number:247-074-2
UNII:H8558L43SR
DSSTox Substance ID:DTXSID30904360
Nikkaji Number:J17.244H
Wikipedia:Jasmine_lactone
Wikidata:Q27279750
Mol file:100428-67-9.mol

Synonyms:Jasmine lactone;Jasmin lactone;25524-95-2;(Z)-7-DECEN-5-OLIDE;cis-Jasmin lactone;FEMA No. 3745;Jasmolactone, delta-;2H-Pyran-2-one, tetrahydro-6-(2-pentenyl)-, (Z)-;2H-Pyran-2-one, tetrahydro-6-(2Z)-2-penten-1-yl-;6-[(Z)-pent-2-enyl]oxan-2-one;UNII-H8558L43SR;Dec-7-en-5-olide, (Z)-;5-(2-Pentenyl)pentanolide, cis-;H8558L43SR;2H-Pyran-2-one, tetrahydro-6-(2Z)-2-pentenyl-;EINECS 247-074-2;(Z)-6-(pent-2-en-1-yl)tetrahydro-2H-pyran-2-one;cis-7-decen-5-olide;5-Hydroxy-7-decenoic acid delta-lactone;5-Hydroxy-7(Z)-decenoic acid delta-lactone;5-Hydroxy-7(Z)-decenoic acid-delta-lactone;Tetrahydro-6-(cis-2-pentenyl)-2H-pyran-2-one;(Z)-Tetrahydro-6-(2-pentenyl)-2H-pyran-2-one;Jasminlactone;creamy lactone;Tetrahydro-6-(2-pentenyl)-2H-pyran-2-one, (Z)-;2H-Pyran-2-one, tetrahydro-6-((Z)-2-penten-1-yl)-;Dec-7(Z)-en-5-olide;(Z)-Dec-7-en-5-olide;cis-7-Decen-5-olid;tetrahydro-6-(2z)-2-pentenyl-2h-pyran-2-one;.delta.-Jasmine lactone;Jasmolactone, .delta.-;Tetrahydro-6-(2Z)-2-penten-1-yl-2H-Pyran-2-one;SCHEMBL2939421;DTXSID30904360;CHEBI:180915;XPPALVZZCMPTIV-ARJAWSKDSA-N;(z)-7-decen-5-olide, AldrichCPR;AKOS040752161;BS-50890;5-Hydroxy-7(Z)-decenoic acid-.delta.-lactone;E83851;Q27279750;5-HYDROXY-7-DECENOIC ACID .DELTA.-LACTONE [FHFI];(Z) - tetrahydro - 6 - (2 - pentenyl) - 2H - pyran - 2 - one

Suppliers and Price of Jasmine lactone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Jasmine lactone

Chemical Property:

XLogP3:2.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:168.115029749
Heavy Atom Count:12
Complexity:173

Purity/Quality:: 98%min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CCC=CCC1CCCC(=O)O1
Isomeric SMILES:CC/C=C\CC1CCCC(=O)O1

Technology Process of Jasmine lactone

There total 23 articles about Jasmine lactone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 25448-66-2
6-(2-pentynyl)-tetrahydro-2-pyranone

: 25524-95-2,100428-67-9,68170-58-1
Jasmin lactone

Guidance literature:: With hydrogen; Lindlar's catalyst;
DOI:10.1246/cl.1983.911

Reference yield: 8.0%

: 42537-02-0,157357-32-9,157357-33-0,51608-18-5
2-<(Z)-2-pentenyl>cyclopentanone

: 25524-95-2,100428-67-9,68170-58-1
Jasmin lactone

: 87611-61-8,173339-06-5,173339-07-6
(Z)-5-Hydroxy-dec-7-enoic acid

Guidance literature:: With bis-trimethylsilanyl peroxide; boron trifluoride diethyl etherate; In dichloromethane; at 25 ℃; for 4.5h;
DOI:10.1246/bcsj.56.2029

Reference yield:

: 16400-32-1
1-bromo-pent-2-yne

: 25524-95-2,100428-67-9,68170-58-1
Jasmin lactone

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) LDA / 1.) THF, hexane, -10 deg C, 15 min, 2.) THF, hexane, -50 deg C, 6 h

2: Al₂O₃ / diethyl ether / 6 h / Ambient temperature

3: 99 percent / O₂, methylene blue / methanol / 3 h / 0 °C / Irradiation

4: NaBH₄, NaHCO₃ / H₂O / 2 h / Ambient temperature

5: p-TsOH / benzene / Heating

6: 90 percent / H₂, quinoline / 5percent Pd/BaSO₄ / benzene

With quinoline; aluminum oxide; sodium tetrahydroborate; hydrogen; oxygen; methylene blue; sodium hydrogencarbonate; toluene-4-sulfonic acid; lithium diisopropyl amide; Pd-BaSO₄; In methanol; diethyl ether; water; benzene;
DOI:10.1021/jo00356a035