hydroxy{[(4-nitrophenyl)sulfonyl]oxy}phenyl-lambda~3~-iodane

Base Information

• Chemical Name: hydroxy{[(4-nitrophenyl)sulfonyl]oxy}phenyl-lambda~3~-iodane
• CAS No.: 61477-33-6
• Molecular Formula: C₁₂H₁₀INO₆S
• Molecular Weight: 423.185
• Mol file: 61477-33-6.mol

Synonyms:

Chemical Property of hydroxy{[(4-nitrophenyl)sulfonyl]oxy}phenyl-lambda~3~-iodane

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of hydroxy{[(4-nitrophenyl)sulfonyl]oxy}phenyl-lambda~3~-iodane

There total 1 articles about hydroxy{[(4-nitrophenyl)sulfonyl]oxy}phenyl-lambda~3~-iodane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ [hydroxy(p-nitrobenezenesulfonyloxy)iodo]benzene (61477-33-6)

Guidance literature:

DOI:10.1021/jo00428a052

Reference yield: 72.0%

4-hydroxy[1]benzopyran-2-one (1076-38-6,92395-12-5) + [hydroxy(p-nitrobenezenesulfonyloxy)iodo]benzene (61477-33-6) → 4-hydroxy-2-oxo-2H-chromen-3-yl 4-nitrobenzenesulfonate

Guidance literature:

In 1,2-dimethoxyethane; at 35 ℃; for 1h;

DOI:10.1021/acs.joc.9b01323

Reference yield: 42.0%

8-methyl-5-nitroquinoline (64976-62-1) + [hydroxy(p-nitrobenezenesulfonyloxy)iodo]benzene (61477-33-6) → (5-nitroquinolin-8-yl)methyl 4-nitrobenzenesulfonate

Guidance literature:

With palladium diacetate; In 1,4-dioxane; at 20 ℃; for 16h; Schlenk technique;

DOI:10.1021/acs.joc.9b01278

Downstream raw materials:

4-Nitro-benzenesulfonic acid 2-(4-chloro-phenyl)-1-methyl-2-oxo-ethyl ester

4-Nitro-benzenesulfonic acid 2-(4-bromo-phenyl)-1-methyl-2-oxo-ethyl ester

4-Nitro-benzenesulfonic acid 2-(4-benzyloxy-phenyl)-1-methyl-2-oxo-ethyl ester

4-Nitro-benzenesulfonic acid 1-oxo-indan-2-yl ester