tetra-O-acetyl-2-phenyl-1,5-anhydro-D-glucitol

Base Information

• Chemical Name: tetra-O-acetyl-2-phenyl-1,5-anhydro-D-glucitol
• CAS No.: 118916-88-4
• Molecular Formula: C₂₀H₂₄O₉
• Molecular Weight: 408.405
• Mol file: 118916-88-4.mol

Synonyms:

Chemical Property of tetra-O-acetyl-2-phenyl-1,5-anhydro-D-glucitol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetra-O-acetyl-2-phenyl-1,5-anhydro-D-glucitol

There total 2 articles about tetra-O-acetyl-2-phenyl-1,5-anhydro-D-glucitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

phenyllithium (591-51-5) + 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl chloride (4451-35-8) → tetra-O-acetyl-2-phenyl-1,5-anhydro-D-glucitol (100545-94-6,118916-88-4) + (2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)benzene (13231-13-5)

Guidance literature:

With diethyl ether; Hydrolysis_.anschliessend Acetylierung;

DOI:10.1021/ja01160a087 DOI:10.1021/jo01033a042

Reference yield:

→ tetra-O-acetyl-2-phenyl-1,5-anhydro-D-glucitol (100545-94-6,118916-88-4)

Guidance literature:

Glucosen-1-tetraacetat, Et2O: 1) PhLi, Et2O (2.5h 20grad, dann 3h Kochen) 2) Acetylierung;

DOI:10.1021/jo01033a042

Reference yield:

tetra-O-acetyl-2-phenyl-1,5-anhydro-D-glucitol (100545-94-6,118916-88-4) → 2-phenyl-1,5-anhydro-D-glucitol (95707-85-0,118916-89-5)

Guidance literature:

With methanol; sodium methylate;

DOI:10.1021/ja01160a087

upstream raw materials:

phenyllithium

2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl chloride

Downstream raw materials:

2-phenyl-1,5-anhydro-D-glucitol