[(E),(S)-2,5,5-trimethylhex-3-enyloxymethyl]benzene

Base Information

Chemical Name:[(E),(S)-2,5,5-trimethylhex-3-enyloxymethyl]benzene
CAS No.:1403577-34-3
Molecular Formula:C₁₆H₂₄O
Molecular Weight:232.366
Hs Code.:

Synonyms:

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Chemical Property of [(E),(S)-2,5,5-trimethylhex-3-enyloxymethyl]benzene

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Technology Process of [(E),(S)-2,5,5-trimethylhex-3-enyloxymethyl]benzene

There total 3 articles about [(E),(S)-2,5,5-trimethylhex-3-enyloxymethyl]benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

: 558-37-2
tert-butylethylene

: 654071-49-5
(-)-(((S)-2-methylbut-3-enyloxy)methyl)benzene

: 1403577-34-3
[(E),(S)-2,5,5-trimethylhex-3-enyloxymethyl]benzene

Guidance literature:: With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; for 16h; Reflux;
DOI:10.1021/ol302541j DOI:10.1021/ol302541j

Reference yield:

: 89358-30-5
benzyl (2E)-4-bromobut-2-en-1-yl ether

: 1403577-34-3
[(E),(S)-2,5,5-trimethylhex-3-enyloxymethyl]benzene

Guidance literature:: Multi-step reaction with 2 steps

1: copper(I) bromide dimethylsulfide complex; (R,Rp)-1-(2-(diphenylphosphino)ferrocenyl)-1-(2-diphenylphosphinophenyl)-N,N-dimethylmethanamine / dichloromethane / 36 h / -78 °C / Inert atmosphere

2: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / 16 h / Reflux

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; copper(I) bromide dimethylsulfide complex; (R,Rp)-1-(2-(diphenylphosphino)ferrocenyl)-1-(2-diphenylphosphinophenyl)-N,N-dimethylmethanamine; In dichloromethane;
DOI:10.1021/ol302541j DOI:10.1021/ol302541j

Reference yield:

: 100-51-6,185532-71-2
benzyl alcohol

: 1403577-34-3
[(E),(S)-2,5,5-trimethylhex-3-enyloxymethyl]benzene

Guidance literature:: Multi-step reaction with 3 steps

1: sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate / dichloromethane / 16 h / Inert atmosphere

2: copper(I) bromide dimethylsulfide complex; (R,Rp)-1-(2-(diphenylphosphino)ferrocenyl)-1-(2-diphenylphosphinophenyl)-N,N-dimethylmethanamine / dichloromethane / 36 h / -78 °C / Inert atmosphere

3: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / 16 h / Reflux

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; copper(I) bromide dimethylsulfide complex; (R,Rp)-1-(2-(diphenylphosphino)ferrocenyl)-1-(2-diphenylphosphinophenyl)-N,N-dimethylmethanamine; tetra(n-butyl)ammonium hydrogensulfate; sodium hydroxide; In dichloromethane;
DOI:10.1021/ol302541j DOI:10.1021/ol302541j