{(CH2Ph)2C2B4H4}Fe(η6-C8H10)

Base Information

• Chemical Name: {(CH2Ph)2C2B4H4}Fe(η6-C8H10)
• CAS No.: 105472-15-9
• Molecular Formula: C₂₄H₂₈B₄Fe
• Molecular Weight: 415.577
• Mol file: 105472-15-9.mol

Synonyms:

Chemical Property of {(CH2Ph)2C2B4H4}Fe(η6-C8H10)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {(CH2Ph)2C2B4H4}Fe(η6-C8H10)

There total 1 articles about {(CH2Ph)2C2B4H4}Fe(η6-C8H10) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.1%

Na(1+)*((C6H5CH2)2C2B4H5)(1-) + dipotassium cyclooctatetraenide (34480-05-2) + iron(II) chloride → ((CH2C6H5)2C2B4H4)Fe(CHCHCHCHCHCHCH2CH2) (105472-15-9) + (C16H18)(2-)*Fe(C6H5CH2)2C2B4H4(2+)=(C16H18)Fe(C6H5CH2)2C2B4H4

Guidance literature:

In tetrahydrofuran; byproducts: hydrogen; Soln. of K2C8H8 was filtered onto anhydrous FeCl2 in a flask immersed in liquid N2, then soln. of carborane was added; mixt. was slowly warmed to -63°C over 3 h with stirring; mixt. then was warmed to room temp. and was stirred for 12 h;; The flask was filled with dry N2 at 1 atm and opened to the air; chromy. on silica column, eluent CH2Cl2-hexane; recrystd. from CH2Cl2;;

Reference yield: 43.1%

((CH2C6H5)2C2B4H4)Fe(CHCHCHCHCHCHCH2CH2) (105472-15-9) + chromium(0) hexacarbonyl (199620-14-9,13007-92-6) → (2,3{(CO)3Cr(η6-C6H5)CH2}2-2,3-C2B4H4)Fe(η6-C8H10) (105501-00-6) + {2-((CO)3Cr(η6-C6H5CH2))-3-(PhCH2)-2,3-C2B4H4}Fe(η6-C8H10) (105472-19-3)

Guidance literature:

In tetrahydrofuran; dibutyl ether; Mixt. of reagents was placed into a Pyrex tube, anhydrous dibutyl ether and THF were added, mixt. was refluxed for 48 h, then cooled to room temp.;; Chromy. on silica column, eluent CH2Cl2-hexane;

Reference yield: 34.2%

9H-fluorene (86-73-7) + ((CH2C6H5)2C2B4H4)Fe(CHCHCHCHCHCHCH2CH2) (105472-15-9) → (η6-C13H10)Fe{(PhCH2)2C2B4H4} (105472-18-2)

Guidance literature:

In neat (no solvent); Reactants were placed into a Pyrex tube, the tube was evacuated, sealed and heated to 175°C for 6 h, then was colled to room temp.;; The reactor was opened to the air, exctd. with CH2Cl2, chromd. on silica column; eluent CH2Cl2-hexane;;

upstream raw materials:

dipotassium cyclooctatetraenide

Downstream raw materials:

(η6-C14H12)Fe{(PhCH2)2C2B4H4}

(η6,η6-C14H12)Fe2{(PhCH2)2C2B4H4}2

(C₁₆H₁₆)Fe(C₆H₅CH₂)2C₂B₄H₄

(η6-C13H10)Fe{(PhCH2)2C2B4H4}

Refernces