ethyl trans-(+)-(3R,4R)-4-benzyl-5-oxo-3-tetrahydrofurancarboxylate

Base Information

• Chemical Name: ethyl trans-(+)-(3R,4R)-4-benzyl-5-oxo-3-tetrahydrofurancarboxylate
• CAS No.: 1155859-92-9
• Molecular Formula: C₁₄H₁₆O₄
• Molecular Weight: 248.279

Synonyms:

Chemical Property of ethyl trans-(+)-(3R,4R)-4-benzyl-5-oxo-3-tetrahydrofurancarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ethyl trans-(+)-(3R,4R)-4-benzyl-5-oxo-3-tetrahydrofurancarboxylate

There total 3 articles about ethyl trans-(+)-(3R,4R)-4-benzyl-5-oxo-3-tetrahydrofurancarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

ethyl trans-4-benzyl-5-oxo-3-tetrahydrofurancarboxylate → trans-(-)-(3S,4S)-4-benzyl-5-oxo-3-tetrahydrofurancarboxylic acid (1155859-90-7) + trans-(+)-(3R,4R)-4-benzyl-5-oxo-3-tetrahydrofurancarboxylic acid + ethyl trans-(+)-(3R,4R)-4-benzyl-5-oxo-3-tetrahydrofurancarboxylate (1155859-92-9)

Guidance literature:

ethyl trans-4-benzyl-5-oxo-3-tetrahydrofurancarboxylate; With sodium hydroxide; α-chymotrypsin; In water; for 8.5h; pH=7.4; aq. phosphate buffer; Enzymatic reaction;

With hydrogenchloride; water; pH=2; optical yield given as %ee; regioselective reaction;

DOI:10.1016/j.tetasy.2009.01.027

Reference yield: 13.0%

ethyl trans-4-benzyl-5-oxo-3-tetrahydrofurancarboxylate → trans-(-)-(3S,4S)-4-benzyl-5-oxo-3-tetrahydrofurancarboxylic acid (1155859-90-7) + ethyl trans-(-)-(3S,4S)-4-benzyl-5-oxo-3-tetrahydrofurancarboxylate + ethyl trans-(+)-(3R,4R)-4-benzyl-5-oxo-3-tetrahydrofurancarboxylate (1155859-92-9)

Guidance literature:

ethyl trans-4-benzyl-5-oxo-3-tetrahydrofurancarboxylate; With sodium hydroxide; α-chymotrypsin; In water; at 20 ℃; for 0.933333h; pH=7.4; aq. phosphate buffer; Enzymatic reaction;

With hydrogenchloride; water; pH=2; optical yield given as %ee; regioselective reaction;

DOI:10.1016/j.tetasy.2009.01.027

Reference yield:

ethyl cis-4-benzyl-5-oxo-3-tetrahydrofurancarboxylate → trans-(-)-(3S,4S)-4-benzyl-5-oxo-3-tetrahydrofurancarboxylic acid (1155859-90-7) + trans-(+)-(3R,4R)-4-benzyl-5-oxo-3-tetrahydrofurancarboxylic acid + ethyl trans-(-)-(3S,4S)-4-benzyl-5-oxo-3-tetrahydrofurancarboxylate + ethyl trans-(+)-(3R,4R)-4-benzyl-5-oxo-3-tetrahydrofurancarboxylate (1155859-92-9)

Guidance literature:

ethyl cis-4-benzyl-5-oxo-3-tetrahydrofurancarboxylate; With Candida cylindracea lipase; sodium hydroxide; In water; at 20 ℃; for 1.3h; pH=7.4; aq. phosphate buffer; Enzymatic reaction;

With hydrogenchloride; water; pH=2; optical yield given as %ee; regioselective reaction;

DOI:10.1016/j.tetasy.2009.01.027

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 1155859-92-9 ethyl trans-(+)-(3R,4R)-4-benzyl-5-oxo-3-tetrahydrofurancarboxylate

Send

Send

Metric Ton KG G Pound L ML

Send

Send