C₂₆H₂₆N₄O₁₄

Base Information

Chemical Name:C₂₆H₂₆N₄O₁₄
CAS No.:113195-31-6
Molecular Formula:C₂₆H₂₆N₄O₁₄
Molecular Weight:618.511
Hs Code.:

C<sub>26</sub>H<sub>26</sub>N<sub>4</sub>O<sub>14</sub>

Synonyms:

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Chemical Property of C₂₆H₂₆N₄O₁₄

Chemical Property:

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Technology Process of C₂₆H₂₆N₄O₁₄

There total 89 articles about C₂₆H₂₆N₄O₁₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 7250-55-7
dimethyl 3-hydroxypentanedioate

: 113195-31-6,113299-86-8,113301-16-9,113565-08-5
C₂₆H₂₆N₄O₁₄

Guidance literature:: Multi-step reaction with 18 steps

1: p-TsOH*H₂O / diethyl ether

2: LiAlH₄ / diethyl ether

3: p-TsOH*H₂O / methanol

4: 98.3 g / p-TsOH*H₂O / acetone

5: 97 percent / pyridinium chlorochromate, MS (3 Angstroem) / CH₂Cl₂

6: 64 percent / p-TsOH*H₂O / CH₂Cl₂ / Heating

7: 72 percent / pyridinium dichromate, MS (3 Angstroem) / CH₂Cl₂

8: 1.) LDA, HMPA, 2.) HMPA / 1.) hexane/THF, -76 -72 deg C, 13 min, then -35 deg C, 2.) -78 deg C, 15 min

9: 11 percent / sucrose, phosphate buffer, baker's yeast, 0.2 percent Triton -100 aq. / 1 h / 30 °C

10: p-TsOH*H₂O / ethanol; H₂O / 168 h / Ambient temperature

11: 4-(N,N-dimethylamino)pyridine / pyridine

12: 97 percent / LAH / diethyl ether

13: 80 percent / NaH (60 percent), n-Bu₄N⁽¹⁺⁾*I^(1-) / paraffin; tetrahydrofuran / 1 h / Heating

14: acetonitrile / 1 h / Heating

15: 1.) HMPA, n-BuLi / 1.) THF/n-hexane, -67 deg C, 30 min, 2.) THF, -67 -63 deg C, then room temperature, 3 h 50 min and 6 h 15 min

16: HCl, H₂O / tetrahydrofuran / 15 h / Ambient temperature

17: 75 percent / Na, liq. NH₃ / tetrahydrofuran

18: 18 percent / DMAP / pyridine / 72 h / Ambient temperature

With hydrogenchloride; N,N,N,N,N,N-hexamethylphosphoric triamide; dmap; lithium aluminium tetrahydride; dipyridinium dichromate; n-butyllithium; baker's yeast; phosphate buffer; MS (3 Angstroem); Triton -100; ammonia; water; sodium; tetra-(n-butyl)ammonium iodide; sodium hydride; toluene-4-sulfonic acid; pyridinium chlorochromate; lithium diisopropyl amide; Sucrose; toluene-4-sulfonic acid; In tetrahydrofuran; pyridine; methanol; diethyl ether; ethanol; dichloromethane; water; acetone; acetonitrile; paraffin;
DOI:10.1016/S0040-4020(01)89929-4

Reference yield:

: 7250-55-7
dimethyl 3-hydroxypentanedioate

: 113195-31-6,113299-86-8,113301-16-9,113565-08-5
C₂₆H₂₆N₄O₁₄

Guidance literature:: Multi-step reaction with 16 steps

1: p-TsOH*H₂O / diethyl ether

2: LiAlH₄ / diethyl ether

3: p-TsOH*H₂O / methanol

4: 98.3 g / p-TsOH*H₂O / acetone

5: 97 percent / pyridinium chlorochromate, MS (3 Angstroem) / CH₂Cl₂

6: 64 percent / p-TsOH*H₂O / CH₂Cl₂ / Heating

7: 72 percent / pyridinium dichromate, MS (3 Angstroem) / CH₂Cl₂

8: 1.) LDA, HMPA, 2.) HMPA / 1.) hexane/THF, -76 -72 deg C, 13 min, then -35 deg C, 2.) -78 deg C, 15 min

9: 11 percent / sucrose, phosphate buffer, baker's yeast, 0.2 percent Triton -100 aq. / 1 h / 30 °C

10: p-TsOH*H₂O / ethanol; H₂O / 168 h / Ambient temperature

11: 4-(N,N-dimethylamino)pyridine / pyridine

12: 97 percent / LAH / diethyl ether

13: 80 percent / NaH (60 percent), n-Bu₄N⁽¹⁺⁾*I^(1-) / paraffin; tetrahydrofuran / 1 h / Heating

14: acetonitrile / 1 h / Heating

15: 1.) HMPA, n-BuLi / 1.) THF/n-hexane, -67 deg C, 30 min, 2.) THF, -67 -63 deg C, then room temperature, 3 h 50 min and 6 h 15 min

16: 2d and 24d not separated

With N,N,N,N,N,N-hexamethylphosphoric triamide; dmap; lithium aluminium tetrahydride; dipyridinium dichromate; n-butyllithium; baker's yeast; phosphate buffer; MS (3 Angstroem); Triton -100; tetra-(n-butyl)ammonium iodide; sodium hydride; toluene-4-sulfonic acid; pyridinium chlorochromate; lithium diisopropyl amide; Sucrose; toluene-4-sulfonic acid; In tetrahydrofuran; pyridine; methanol; diethyl ether; ethanol; dichloromethane; water; acetone; acetonitrile; paraffin;
DOI:10.1016/S0040-4020(01)89929-4

Reference yield:

: 113195-22-5
(2R,3S)-2-allylbutane-1,3-diol 3-THP ether

: 113195-31-6,113299-86-8,113301-16-9,113565-08-5
C₂₆H₂₆N₄O₁₄

Guidance literature:: Multi-step reaction with 11 steps

1: 59.7 g / NaH 60 percent , n-Bu₄N⁽¹⁺⁾*I^(1-) / paraffin; tetrahydrofuran / 3 h / Heating

2: p-TsOH*H₂O / methanol

3: DMAP / pyridine

4: 1.) LiBEt₃H, 2.) 3 N NaOH aq., 35 percent H₂O₂ aq. / 1.) THF, -5 deg C, then reflux, 20 min, 2.) H₂O, 50 deg C, then 30 min, room temperature

5: 7.3 g / liq. NH₃, Na / tetrahydrofuran / 0.17 h / Heating

6: PPTS / CH₂Cl₂

7: 65 percent / 1.) NaIO₄, 5 percent OsO₄, 2.) NaIO₄ / diethyl ether; H₂O; tetrahydrofuran / 1.) 2 h, room temperature, 2.) 5.5 h, room temperature

8: 1.) HMPA, n-BuLi / 1.) THF/n-hexane, -67 deg C, 30 min, 2.) THF, -67 -63 deg C, then room temperature, 3 h 50 min and 6 h 15 min

9: HCl, H₂O / tetrahydrofuran / 15 h / Ambient temperature

10: 75 percent / Na, liq. NH₃ / tetrahydrofuran

11: 18 percent / DMAP / pyridine / 72 h / Ambient temperature

With hydrogenchloride; N,N,N,N,N,N-hexamethylphosphoric triamide; dmap; sodium hydroxide; sodium periodate; osmium(VIII) oxide; n-butyllithium; ammonia; water; dihydrogen peroxide; sodium; pyridinium p-toluenesulfonate; tetra-(n-butyl)ammonium iodide; sodium hydride; lithium triethylborohydride; toluene-4-sulfonic acid; In tetrahydrofuran; pyridine; methanol; diethyl ether; dichloromethane; water; paraffin;
DOI:10.1016/S0040-4020(01)89929-4