2-O-benzyl-3,5-O-(tetraisopropylsiloxane-1,3-diyl)-β-D-arabinofuranosyl-(1->2)-3,5-di-O-benzyl-α-D-arabinofuranosyl-(1->5)-[2-O-benzyl-3,5-O-(tetraisopropylsiloxane-1,3-diyl)-β-D-arabinofuranosyl-(1->2)-3,5-di-O-benzyl-α-D-arabinofuranosyl]-(1->3)-2-O-benzyl-α-D-arabinofuranosyl-(1->5)-2,3-di-O-benzyl-α-D-arabinofuranosyl-(1->5)-3-O-benzyl-1,2-O-isopropylidene-β-D-arabinofuranose

Base Information

• Chemical Name: 2-O-benzyl-3,5-O-(tetraisopropylsiloxane-1,3-diyl)-β-D-arabinofuranosyl-(1->2)-3,5-di-O-benzyl-α-D-arabinofuranosyl-(1->5)-[2-O-benzyl-3,5-O-(tetraisopropylsiloxane-1,3-diyl)-β-D-arabinofuranosyl-(1->2)-3,5-di-O-benzyl-α-D-arabinofuranosyl]-(1->3)-2-O-benzyl-α-D-arabinofuranosyl-(1->5)-2,3-di-O-benzyl-α-D-arabinofuranosyl-(1->5)-3-O-benzyl-1,2-O-isopropylidene-β-D-arabinofuranose
• CAS No.: 1268604-04-1
• Molecular Formula: C₁₃₂H₁₇₄O₃₁Si₄
• Molecular Weight: 2369.16
• Mol file: 1268604-04-1.mol

Synonyms:

Chemical Property of 2-O-benzyl-3,5-O-(tetraisopropylsiloxane-1,3-diyl)-β-D-arabinofuranosyl-(1->2)-3,5-di-O-benzyl-α-D-arabinofuranosyl-(1->5)-[2-O-benzyl-3,5-O-(tetraisopropylsiloxane-1,3-diyl)-β-D-arabinofuranosyl-(1->2)-3,5-di-O-benzyl-α-D-arabinofuranosyl]-(1->3)-2-O-benzyl-α-D-arabinofuranosyl-(1->5)-2,3-di-O-benzyl-α-D-arabinofuranosyl-(1->5)-3-O-benzyl-1,2-O-isopropylidene-β-D-arabinofuranose

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-O-benzyl-3,5-O-(tetraisopropylsiloxane-1,3-diyl)-β-D-arabinofuranosyl-(1->2)-3,5-di-O-benzyl-α-D-arabinofuranosyl-(1->5)-[2-O-benzyl-3,5-O-(tetraisopropylsiloxane-1,3-diyl)-β-D-arabinofuranosyl-(1->2)-3,5-di-O-benzyl-α-D-arabinofuranosyl]-(1->3)-2-O-benzyl-α-D-arabinofuranosyl-(1->5)-2,3-di-O-benzyl-α-D-arabinofuranosyl-(1->5)-3-O-benzyl-1,2-O-isopropylidene-β-D-arabinofuranose

There total 1 articles about 2-O-benzyl-3,5-O-(tetraisopropylsiloxane-1,3-diyl)-β-D-arabinofuranosyl-(1->2)-3,5-di-O-benzyl-α-D-arabinofuranosyl-(1->5)-[2-O-benzyl-3,5-O-(tetraisopropylsiloxane-1,3-diyl)-β-D-arabinofuranosyl-(1->2)-3,5-di-O-benzyl-α-D-arabinofuranosyl]-(1->3)-2-O-benzyl-α-D-arabinofuranosyl-(1->5)-2,3-di-O-benzyl-α-D-arabinofuranosyl-(1->5)-3-O-benzyl-1,2-O-isopropylidene-β-D-arabinofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3,5-di-O-benzyl-α-D-arabinofuranosyl-(1->5)-(3,5-di-O-benzyl-α-D-arabinofuranosyl)-(1->3)-2-O-benzyl-α-D-arabinofuranosyl-(1->5)-2,3-di-O-benzyl-α-D-arabinofuranosyl-(1->5)-3-O-benzyl-1,2-O-isopropylidene-β-D-arabinofuranose (1268603-98-0) + p-tolyl 2-O-benzyl-3,5-O-(tetraisopropylsiloxane-1,3-diyl)-1-thio-α-D-arabinofuranoside (917590-96-6) → 2-O-benzyl-3,5-O-(tetraisopropylsiloxane-1,3-diyl)-D-arabinofuranosyl-(1->2)-3,5-di-O-benzyl-α-D-arabinofuranosyl-(1->5)-[2-O-benzyl-3,5-O-(tetraisopropylsiloxane-1,3-diyl)-D-arabinofuranosyl-(1->2)-3,5-di-O-benzyl-α-D-arabinofuranosyl]-(1->3)-2-O-benzyl-α-D-arabinofuranosyl-(1->5)-2,3-di-O-benzyl-α-D-arabinofuranosyl-(1->5)-3-O-benzyl-1,2-O-isopropylidene-β-D-arabinofuranose + 2-O-benzyl-3,5-O-(tetraisopropylsiloxane-1,3-diyl)-β-D-arabinofuranosyl-(1->2)-3,5-di-O-benzyl-α-D-arabinofuranosyl-(1->5)-[2-O-benzyl-3,5-O-(tetraisopropylsiloxane-1,3-diyl)-β-D-arabinofuranosyl-(1->2)-3,5-di-O-benzyl-α-D-arabinofuranosyl]-(1->3)-2-O-benzyl-α-D-arabinofuranosyl-(1->5)-2,3-di-O-benzyl-α-D-arabinofuranosyl-(1->5)-3-O-benzyl-1,2-O-isopropylidene-β-D-arabinofuranose (1268604-04-1)

Guidance literature:

With N-iodo-succinimide; silver trifluoromethanesulfonate; In dichloromethane; at -40 ℃; for 4h; optical yield given as %de; stereoselective reaction; Molecular sieve; Inert atmosphere;

DOI:10.1021/ja109932t

upstream raw materials:

3,5-di-O-benzyl-α-D-arabinofuranosyl-(1->5)-(3,5-di-O-benzyl-α-D-arabinofuranosyl)-(1->3)-2-O-benzyl-α-D-arabinofuranosyl-(1->5)-2,3-di-O-benzyl-α-D-arabinofuranosyl-(1->5)-3-O-benzyl-1,2-O-isopropylidene-β-D-arabinofuranose

p-tolyl 2-O-benzyl-3,5-O-(tetraisopropylsiloxane-1,3-diyl)-1-thio-α-D-arabinofuranoside