(κ-C,N,N(py)2-(2-pyridylmethyl)2N(CH2(4-(t)Bu-phenyl-2-yl)))FeBr

Base Information

• Chemical Name: (κ-C,N,N(py)2-(2-pyridylmethyl)2N(CH2(4-(t)Bu-phenyl-2-yl)))FeBr
• CAS No.: 1191437-61-2
• Molecular Formula: C₂₃H₂₆BrFeN₃
• Molecular Weight: 480.231
• Mol file: 1191437-61-2.mol

Synonyms:

Chemical Property of (κ-C,N,N(py)2-(2-pyridylmethyl)2N(CH2(4-(t)Bu-phenyl-2-yl)))FeBr

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (κ-C,N,N(py)2-(2-pyridylmethyl)2N(CH2(4-(t)Bu-phenyl-2-yl)))FeBr

There total 1 articles about (κ-C,N,N(py)2-(2-pyridylmethyl)2N(CH2(4-(t)Bu-phenyl-2-yl)))FeBr which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 16.0%

Fe{N(SiMe3)2}2(tetrahydrofuran) (133984-10-8) + N-(2-bromo-4-tert-butylbenzyl)-1-(pyridine-2-yl)-N-(pyridine-2-ylmethyl)methanamine (1191437-58-7) → (κ-C,N,N(py)2-(2-pyridylmethyl)2N(CH2(4-(t)Bu-phenyl-2-yl)))FeBr (1191437-61-2) + tris[bis(trimethylsilyl)amido]iron(III) (22999-67-3,133009-01-5)

Guidance literature:

In diethyl ether; Et2O transferred (vac., at -78°C) to a flask charged with Fe and Br compds., warmed slowly to 23°C, stirred for 14 h; evapd., triturated with pentane, taken up in C6H6, filtered;

DOI:10.1021/ic901329z

upstream raw materials:

Fe{N(SiMe₃)2}2(tetrahydrofuran)

N-(2-bromo-4-tert-butylbenzyl)-1-(pyridine-2-yl)-N-(pyridine-2-ylmethyl)methanamine