3-(4-(bis(2',4'-bis(hexyloxy)-[1,1'-biphenyl]-4-yl)amino)phenyl)-2-cyanoacrylic acid

Base Information

Chemical Name:3-(4-(bis(2',4'-bis(hexyloxy)-[1,1'-biphenyl]-4-yl)amino)phenyl)-2-cyanoacrylic acid
CAS No.:1403674-51-0
Molecular Formula:C₅₈H₇₂N₂O₆
Molecular Weight:893.219
Hs Code.:

Synonyms:

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Chemical Property of 3-(4-(bis(2',4'-bis(hexyloxy)-[1,1'-biphenyl]-4-yl)amino)phenyl)-2-cyanoacrylic acid

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Technology Process of 3-(4-(bis(2',4'-bis(hexyloxy)-[1,1'-biphenyl]-4-yl)amino)phenyl)-2-cyanoacrylic acid

There total 4 articles about 3-(4-(bis(2',4'-bis(hexyloxy)-[1,1'-biphenyl]-4-yl)amino)phenyl)-2-cyanoacrylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 851228-26-7
1-chloro-2,4-bis(hexyloxy)benzene

: 1403674-51-0
3-(4-(bis(2',4'-bis(hexyloxy)-[1,1'-biphenyl]-4-yl)amino)phenyl)-2-cyanoacrylic acid

Guidance literature:: Multi-step reaction with 4 steps

1: sodium acetate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; XPhos / 1,4-dioxane / 10 h / 95 °C / Inert atmosphere

2: sodium acetate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; XPhos / toluene; water; tert-Amyl alcohol / 10 h / 80 °C / Inert atmosphere

3: potassium phosphate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; XPhos / 1,4-dioxane / 10 h / 75 °C

4: triethylamine; piperidine; magnesium sulfate / dichloromethane / 40 °C / Inert atmosphere

With piperidine; potassium phosphate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; sodium acetate; magnesium sulfate; triethylamine; XPhos; In 1,4-dioxane; tert-Amyl alcohol; dichloromethane; water; toluene;
DOI:10.1039/c2cc35597c

Reference yield:

: 1391734-70-5
2-(2,4-bis(hexyloxy)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 1403674-51-0
3-(4-(bis(2',4'-bis(hexyloxy)-[1,1'-biphenyl]-4-yl)amino)phenyl)-2-cyanoacrylic acid

Guidance literature:: Multi-step reaction with 3 steps

1: sodium acetate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; XPhos / toluene; water; tert-Amyl alcohol / 10 h / 80 °C / Inert atmosphere

2: potassium phosphate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; XPhos / 1,4-dioxane / 10 h / 75 °C

3: triethylamine; piperidine; magnesium sulfate / dichloromethane / 40 °C / Inert atmosphere

With piperidine; potassium phosphate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; sodium acetate; magnesium sulfate; triethylamine; XPhos; In 1,4-dioxane; tert-Amyl alcohol; dichloromethane; water; toluene;
DOI:10.1039/c2cc35597c

Reference yield:

: 111-25-1
1-bromo-hexane

: 1403674-51-0
3-(4-(bis(2',4'-bis(hexyloxy)-[1,1'-biphenyl]-4-yl)amino)phenyl)-2-cyanoacrylic acid

Guidance literature:: Multi-step reaction with 5 steps

1: potassium hydroxide / dimethyl sulfoxide / 0 - 20 °C / Inert atmosphere

2: sodium acetate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; XPhos / 1,4-dioxane / 10 h / 95 °C / Inert atmosphere

3: sodium acetate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; XPhos / toluene; water; tert-Amyl alcohol / 10 h / 80 °C / Inert atmosphere

4: potassium phosphate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; XPhos / 1,4-dioxane / 10 h / 75 °C

5: triethylamine; piperidine; magnesium sulfate / dichloromethane / 40 °C / Inert atmosphere

With piperidine; potassium phosphate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; sodium acetate; magnesium sulfate; triethylamine; potassium hydroxide; XPhos; In 1,4-dioxane; tert-Amyl alcohol; dichloromethane; water; dimethyl sulfoxide; toluene;
DOI:10.1039/c2cc35597c