C₄₅H₅₇NO₁₁Se

Base Information

• Chemical Name: C₄₅H₅₇NO₁₁Se
• CAS No.: 104432-05-5
• Molecular Formula: C₄₅H₅₇NO₁₁Se
• Molecular Weight: 866.908
• Mol file: 104432-05-5.mol

Synonyms:

Chemical Property of C₄₅H₅₇NO₁₁Se

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₄₅H₅₇NO₁₁Se

There total 42 articles about C₄₅H₅₇NO₁₁Se which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(1,2-Dimethyl-propenyloxy)-dimethyl-phenyl-silane (65335-67-3) → C45H57NO11Se (104432-05-5,111266-09-2,111266-10-5)

Guidance literature:

Multi-step reaction with 11 steps

1: 91 percent / TiCl₄ / CH₂Cl₂ / 1 h / -70 °C

2: pyridine / toluene / 1 h / 0 °C

3: LDA / hexane; tetrahydrofuran / 1 h / -70 °C

4: 99 percent / K₂CO₃ / acetone / 1) 2 h, reflux, 2) 1 h, RT

5: 70 percent / DIBAL-H / toluene / 3 h / -70 °C

6: BF₃OEt₂ / CH₂Cl₂ / 1.5 h / 0 °C

7: HCl / tetrahydrofuran / 0.5 h / Ambient temperature

8: CeCl₃ heptahydrate, NaBH₄ / methanol / 0.08 h / -78 °C

9: 74 percent / aq. K₂CO₃ solution (30percent), H₂O₂ (30percent) / ethanol / 1.17 h / Ambient temperature

10: CH₂Cl₂ / 6 h / Ambient temperature

11: Et₃N / CH₂Cl₂ / 2 h / Ambient temperature

With pyridine; hydrogenchloride; sodium tetrahydroborate; cerium(III) chloride; boron trifluoride diethyl etherate; dihydrogen peroxide; titanium tetrachloride; diisobutylaluminium hydride; potassium carbonate; triethylamine; lithium diisopropyl amide; In tetrahydrofuran; methanol; ethanol; hexane; dichloromethane; acetone; toluene;

DOI:10.1016/S0040-4020(01)81981-5

Reference yield:

C12H21ClO5 (94493-08-0,94493-09-1,139403-52-4,139403-64-8) → C45H57NO11Se (104432-05-5,111266-09-2,111266-10-5)

Guidance literature:

Multi-step reaction with 9 steps

1: LDA / hexane; tetrahydrofuran / 1 h / -70 °C

2: 99 percent / K₂CO₃ / acetone / 1) 2 h, reflux, 2) 1 h, RT

3: 70 percent / DIBAL-H / toluene / 3 h / -70 °C

4: BF₃OEt₂ / CH₂Cl₂ / 1.5 h / 0 °C

5: HCl / tetrahydrofuran / 0.5 h / Ambient temperature

6: CeCl₃ heptahydrate, NaBH₄ / methanol / 0.08 h / -78 °C

7: 74 percent / aq. K₂CO₃ solution (30percent), H₂O₂ (30percent) / ethanol / 1.17 h / Ambient temperature

8: CH₂Cl₂ / 6 h / Ambient temperature

9: Et₃N / CH₂Cl₂ / 2 h / Ambient temperature

With hydrogenchloride; sodium tetrahydroborate; cerium(III) chloride; boron trifluoride diethyl etherate; dihydrogen peroxide; diisobutylaluminium hydride; potassium carbonate; triethylamine; lithium diisopropyl amide; In tetrahydrofuran; methanol; ethanol; hexane; dichloromethane; acetone; toluene;

DOI:10.1016/S0040-4020(01)81981-5

Reference yield:

4-Hydroxy-6,7-dimethoxy-3,3-dimethyl-heptan-2-one (94493-07-9,94507-10-5,139403-51-3,139403-63-7) → C45H57NO11Se (104432-05-5,111266-09-2,111266-10-5)

Guidance literature:

Multi-step reaction with 10 steps

1: pyridine / toluene / 1 h / 0 °C

2: LDA / hexane; tetrahydrofuran / 1 h / -70 °C

3: 99 percent / K₂CO₃ / acetone / 1) 2 h, reflux, 2) 1 h, RT

4: 70 percent / DIBAL-H / toluene / 3 h / -70 °C

5: BF₃OEt₂ / CH₂Cl₂ / 1.5 h / 0 °C

6: HCl / tetrahydrofuran / 0.5 h / Ambient temperature

7: CeCl₃ heptahydrate, NaBH₄ / methanol / 0.08 h / -78 °C

8: 74 percent / aq. K₂CO₃ solution (30percent), H₂O₂ (30percent) / ethanol / 1.17 h / Ambient temperature

9: CH₂Cl₂ / 6 h / Ambient temperature

10: Et₃N / CH₂Cl₂ / 2 h / Ambient temperature

With pyridine; hydrogenchloride; sodium tetrahydroborate; cerium(III) chloride; boron trifluoride diethyl etherate; dihydrogen peroxide; diisobutylaluminium hydride; potassium carbonate; triethylamine; lithium diisopropyl amide; In tetrahydrofuran; methanol; ethanol; hexane; dichloromethane; acetone; toluene;

DOI:10.1016/S0040-4020(01)81981-5

upstream raw materials:

Benzoic acid (2R,4R,6S)-2-((S)-2,3-dimethoxy-propyl)-6-methoxycarbonimidoyl-3,3-dimethyl-tetrahydro-pyran-4-yl ester

Benzoic acid (S)-chlorocarbonyl-((2R,4S,5R,6R)-2-methoxy-5,6-dimethyl-4-phenylselanylmethyl-tetrahydro-pyran-2-yl)-methyl ester

(1,2-Dimethyl-propenyloxy)-dimethyl-phenyl-silane

C₁₂H₂₁ClO₅

Downstream raw materials:

C₄₅H₅₉NO₁₁Se

C₄₅H₅₉NO₁₁Se

C₄₅H₅₉NO₁₁Se

C₄₅H₅₉NO₁₁Se