dicarba-nido-decaborane⁽¹²⁾

Base Information

• Chemical Name: dicarba-nido-decaborane⁽¹²⁾
• CAS No.: 86457-95-6
• Molecular Formula: C₂H₁₂B₈
• Molecular Weight: 122.605
• Mol file: 86457-95-6.mol

Synonyms:

Chemical Property of dicarba-nido-decaborane⁽¹²⁾

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dicarba-nido-decaborane⁽¹²⁾

There total 7 articles about dicarba-nido-decaborane⁽¹²⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

dimethylsulfane-nonaborane + acetylene (74-86-2,25067-58-7) → dicarba-nido-decaborane(12) (86457-95-6,41655-26-9)

Guidance literature:

In toluene; byproducts: H2; N2-atmosphere; bubbling H2C2 through soln. of borane (room temp., then refluxing for 15 min); cooling to room temp., distn. off of solvent (vac.), drying (vac., room temp.), sublimation (50°C);

DOI:10.1016/S0022-328X(97)00535-4

Reference yield:

B8H12 + acetylene (74-86-2,25067-58-7) → dicarba-nido-decaborane(12) (86457-95-6,41655-26-9)

Guidance literature:

DOI:10.1021/ja00734a041 DOI:10.1021/ja00800a017

Reference yield:

n-B9H15 + acetylene (74-86-2,25067-58-7) → dicarba-nido-decaborane(12) (86457-95-6,41655-26-9)

Guidance literature:

DOI:10.1021/ja00734a041 DOI:10.1021/ja00800a017

upstream raw materials:

acetylene

Downstream raw materials:

closo-1,10-dicarbadecaborane

1,6-dicarba-closo-decaborane⁽¹⁰⁾

1,2-C₂B₇H₉

1,2-C2B8H10