mer,trans-HRe(CO)3{P(OPh)3}2

Base Information

• Chemical Name: mer,trans-HRe(CO)3{P(OPh)3}2
• CAS No.: 97485-58-0
• Molecular Formula: C₃₉H₃₁O₉P₂Re
• Molecular Weight: 891.824
• Mol file: 97485-58-0.mol

Synonyms:

Chemical Property of mer,trans-HRe(CO)3{P(OPh)3}2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of mer,trans-HRe(CO)3{P(OPh)3}2

There total 2 articles about mer,trans-HRe(CO)3{P(OPh)3}2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 15.0%

triphenyl phosphite (101-02-0) + decacarbonyldirhenium(0) (14285-68-8) → mer,trans-HRe(CO)3{P(OPh)3}2 (97485-58-0) + Re2(CO)6(P(OC6H5)3)4 + Re2(CO)6(P(OC6H5)3)4 + Re2(CO)4(P(OC6H5)3)6 + Re2(CO)7(P(OC6H5)3)3

Guidance literature:

In hexane; byproducts: CO; Irradiation (UV/VIS); (vac.); soln. of Re complex and P(OPh)3 was irradiated (450 W medium pressure mercury lamp) for 10 h; solvent was removed in vac. yielding yellowish green oil, sepn. by TLC chromy. (Kieselgel, hexane/benzene/CHCl3 4/1/1); elem. anal.;

DOI:10.1016/0022-328X(85)87144-8

Reference yield:

formyl mer,trans-Re(CO)3{P(OPh)3}2 → mer,trans-HRe(CO)3{P(OPh)3}2 (97485-58-0)

Guidance literature:

In dichloromethane-d2; decompn. of saturated soln. at room temp. under N2; monitored by (1H)-NMR;

upstream raw materials:

triphenyl phosphite

decacarbonyldirhenium⁽⁰⁾