Au₁₁⁽³⁺⁾8P(C₆H₅)32CNO^(1-)*NO₃^(1-)=Au₁₁(P(C₆H₅)3)8(CNO)2NO₃

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Chemical Name:Au₁₁⁽³⁺⁾*8P(C₆H₅)3*2CNO^(1-)*NO₃^(1-)=Au₁₁(P(C₆H₅)3)8(CNO)2NO₃
CAS No.:98921-33-6
Molecular Formula:2CNO*8C₁₈H₁₅P*NO₃*Au₁₁
Molecular Weight:4411
Hs Code.:

Au<sub>11</sub><sup>(3+)</sup>*8P(C<sub>6</sub>H<sub>5</sub>)3*2CNO<sup>(1-)</sup>*NO<sub>3</sub><sup>(1-)</sup>=Au<sub>11</sub>(P(C<sub>6</sub>H<sub>5</sub>)3)8(CNO)2NO<sub>3</sub>

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Chemical Property of Au₁₁⁽³⁺⁾*8P(C₆H₅)3*2CNO^(1-)*NO₃^(1-)=Au₁₁(P(C₆H₅)3)8(CNO)2NO₃

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Technology Process of Au₁₁⁽³⁺⁾*8P(C₆H₅)3*2CNO^(1-)*NO₃^(1-)=Au₁₁(P(C₆H₅)3)8(CNO)2NO₃

There total 3 articles about Au₁₁⁽³⁺⁾*8P(C₆H₅)3*2CNO^(1-)*NO₃^(1-)=Au₁₁(P(C₆H₅)3)8(CNO)2NO₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

: Au₈⁽²⁺⁾*7(P(C₆H₅)3)*2NO₃^(1-) = Au₈(P(C₆H₅)3)7(NO₃)2

: 98875-32-2
AuP(C₆H₅)3CNO

: 98921-33-6
Au₁₁⁽³⁺⁾*8P(C₆H₅)3*2CNO^(1-)*NO₃^(1-)=Au₁₁(P(C₆H₅)3)8(CNO)2NO₃

Guidance literature:: In dichloromethane; dissolving Au cluster and AuP(C6H5)3CNO in CH2Cl2; storage for 2 weeks in the dark;; chromatography on Sephadex column with acetone; recrystn. by slow diffusion of hexane into CH2Cl2 soln.; elem. anal.;;

Reference yield: 24.0%

: Au₈(PPh₃)₈(NO₃)₂

: 98875-34-4
Na⁽¹⁺⁾*[Au(CNO)2]^(1-)=Na[Au(CNO)2]

: 98921-33-6
Au₁₁⁽³⁺⁾*8P(C₆H₅)3*2CNO^(1-)*NO₃^(1-)=Au₁₁(P(C₆H₅)3)8(CNO)2NO₃

Guidance literature:: In N,N-dimethyl-formamide; dissolving Au cluster in DMF; adding slowly soln. of Na(Au(CNO)2) in DMF with stirring;; addn. of H2O after 30 min; filtration over Kieselguhr; chromatography on Sephadex column with acetone; recrystn. by slow diffusion of hexane into CH2Cl2 soln.; elem. anal.;;

Reference yield: 18.0%

: Au₉(triphenylphosphine)₈(NO₃)₃

: 98921-33-6
Au₁₁⁽³⁺⁾*8P(C₆H₅)3*2CNO^(1-)*NO₃^(1-)=Au₁₁(P(C₆H₅)3)8(CNO)2NO₃

Guidance literature:: With CO; In dichloromethane; byproducts: gold; dissolving Au cluster in CH2Cl2; placing under 7 atm of CO pressure at room temp.; mechanism discussed;; filtration; evapn. to dryness; chromatography on Sephadex column with acetone; recrystn. by slow diffusion of hexane into CH2Cl2 soln.; elem. anal.; NMR spectroscopy;;