zinc(II) 2-(2-hydroxymethylbenzyloxy)-9,10,16,17,23,24-hexaethylphthalocyanine

Base Information

• Chemical Name: zinc(II) 2-(2-hydroxymethylbenzyloxy)-9,10,16,17,23,24-hexaethylphthalocyanine
• CAS No.: 916803-95-7
• Molecular Formula: C₅₂H₄₈N₈O₂Zn
• Molecular Weight: 882.396
• Mol file: 916803-95-7.mol

Synonyms:

Chemical Property of zinc(II) 2-(2-hydroxymethylbenzyloxy)-9,10,16,17,23,24-hexaethylphthalocyanine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of zinc(II) 2-(2-hydroxymethylbenzyloxy)-9,10,16,17,23,24-hexaethylphthalocyanine

There total 1 articles about zinc(II) 2-(2-hydroxymethylbenzyloxy)-9,10,16,17,23,24-hexaethylphthalocyanine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

zinc(II) 9,16,23-tri-tert-butyl-2-nitrophthalocyanine (916803-91-3) + phthalyl alcohol (612-14-6) → zinc(II) 2-(2-hydroxymethylbenzyloxy)-9,10,16,17,23,24-hexaethylphthalocyanine (916803-95-7)

Guidance literature:

With sodium hydride; In dimethyl sulfoxide; mixt. of NaH, benzene-1,2-dimethanol and zinc complex in DMSO was kept at 20-25°C for 30 min; mixt. treated (H2O); ppt. filtered off; washed (H2O, hot MeOH); chromd. on SiO2 (CHCl3-THF as eluent, 50:1);

DOI:10.1007/s11172-006-0083-8

Reference yield: 97.0%

zinc(II) 2-(2-hydroxymethylbenzyloxy)-9,10,16,17,23,24-hexaethylphthalocyanine (916803-95-7) + 4-Nitrophthalonitrile (31643-49-9) → zinc(II) 2-[2-(3,4-dicyanophenoxymethyl)benzyloxy]-9,10,16,17,23,24-tri-tert-butylphthalocyanine (916803-96-8)

Guidance literature:

With sodium hydride; In dimethyl sulfoxide; mixt. of NaH, 4-nitrophthalonitrile, and zinc complex in DMSO was kept at 35-40°C for 6 min; mixt. treated (H2O); ppt. filtered off; washed (H2O, hot MeOH);

DOI:10.1007/s11172-006-0083-8

upstream raw materials:

zinc(II) 9,16,23-tri-tert-butyl-2-nitrophthalocyanine

phthalyl alcohol

Downstream raw materials:

zinc(II) 2-[2-(3,4-dicyanophenoxymethyl)benzyloxy]-9,10,16,17,23,24-tri-tert-butylphthalocyanine