{PhCH₂PPh₃}{Pd(C₆H₂(NO₂)3-2,4,6)(oxalate)(dimethyl sulphoxide)}

Base Information

• Chemical Name: {PhCH₂PPh₃}{Pd(C₆H₂(NO₂)3-2,4,6)(oxalate)(dimethyl sulphoxide)}
• CAS No.: 147557-56-0
• Molecular Formula: C₂H₆OS*C₂O₄*C₆H₂N₃O₆*C₂₅H₂₂P*Pd
• Molecular Weight: 838.096
• Mol file: 147557-56-0.mol

Synonyms:

Chemical Property of {PhCH₂PPh₃}{Pd(C₆H₂(NO₂)3-2,4,6)(oxalate)(dimethyl sulphoxide)}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {PhCH₂PPh₃}{Pd(C₆H₂(NO₂)3-2,4,6)(oxalate)(dimethyl sulphoxide)}

There total 1 articles about {PhCH₂PPh₃}{Pd(C₆H₂(NO₂)3-2,4,6)(oxalate)(dimethyl sulphoxide)} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

cis-{(PhCH2)PPh3}{Pd(C6H2(NO2)3)Cl2(S(O)Me2)} + silver oxalate (15843-43-3,31038-77-4) → {PhCH2PPh3}{Pd(C6H2(NO2)3-2,4,6)(oxalate)(dimethyl sulphoxide)} (147557-56-0)

Guidance literature:

In acetone; addn. of silver oxalate to a soln. of the Pd complex, stirred at room temp.; after 24 h suspn. concd., extd. (CH2Cl2), filtered, concd., addn. of diethyl ether, crystn., elem. anal.;

DOI:10.1016/0022-328X(92)80180-6

upstream raw materials:

silver oxalate