(1,2-bis(diphenylphosphino)ethane)Pt(n-C₃F₇)(CH₃)

Base Information

• Chemical Name: (1,2-bis(diphenylphosphino)ethane)Pt(n-C₃F₇)(CH₃)
• CAS No.: 364376-67-0
• Molecular Formula: C₃₀H₂₇F₇P₂Pt
• Molecular Weight: 777.561
• Mol file: 364376-67-0.mol

Synonyms:

Chemical Property of (1,2-bis(diphenylphosphino)ethane)Pt(n-C₃F₇)(CH₃)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1,2-bis(diphenylphosphino)ethane)Pt(n-C₃F₇)(CH₃)

There total 1 articles about (1,2-bis(diphenylphosphino)ethane)Pt(n-C₃F₇)(CH₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

(tetramethylenediamine)Pt(n-C3F7)(CH3) (364376-58-9) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → (1,2-bis(diphenylphosphino)ethane)Pt(n-C3F7)(CH3) (364376-67-0)

Guidance literature:

In toluene; under N2 atm. soln. (TMEDA)Pt(n-C3F7)Me and DPPE in toluene was heated under reflux for 3 h; soln. was reduced in vacuo, ppt. was washed with EtOH and hexane; elem. anal.;

DOI:10.1021/om010424h

Reference yield: 94.0%

(1,2-bis(diphenylphosphino)ethane)Pt(n-C3F7)(CH3) (364376-67-0) + trifluorormethanesulfonic acid (1493-13-6) → (1,2-bis(diphenylphosphino)ethane)Pt(n-C3F7)OTf (364376-68-1)

Guidance literature:

In dichloromethane; under N2 atm. CF3SO3H was added to soln.(DPPE)Pt(n-C3F7)(CH3) in CH2Cl2 and stirred for 16 h; soln. was concd. in vacuo, residue was dissolved in CH2Cl2, filtered through Celite, toluene was added, CH2Cl2 was removed in vacuo, ppt. was washed with toluene; elem. anal.;

DOI:10.1021/om010424h

Reference yield: 77.0%

(1,2-bis(diphenylphosphino)ethane)Pt(n-C3F7)(CH3) (364376-67-0) + iodine (7553-56-2,12190-71-5,8031-47-8) → (1,2-bis(diphenylphosphino)ethane)Pt(n-C3F7)I (364376-71-6)

Guidance literature:

In hexane; under N2 atm. suspn. (DPPE)Pt(n-C3F7)(CH3) and I2 in hexane was stirred for 16 h; ppt. was filtered and recrystd. from CH2Cl2/EtOH;

DOI:10.1021/om010424h

upstream raw materials:

(tetramethylenediamine)Pt(n-C₃F₇)(CH₃)

1,2-bis-(diphenylphosphino)ethane

Downstream raw materials:

(1,2-bis(diphenylphosphino)ethane)Pt(n-C₃F₇)I

(1,2-bis(diphenylphosphino)ethane)Pt(n-C₃F₇)OTf

(1,2-bis(diphenylphosphino)ethane)Pt(n-C₃F₇)H