1-(1-carboxylato-2-phenyl-3-benzoylpropyl)-3-(2',6'-dimethyl-3',5'-diethoxycarbonyl-1',4'-dihydro-4'-pyridyl)pyridinium

Base Information

• Chemical Name: 1-(1-carboxylato-2-phenyl-3-benzoylpropyl)-3-(2',6'-dimethyl-3',5'-diethoxycarbonyl-1',4'-dihydro-4'-pyridyl)pyridinium
• CAS No.: 200926-86-9
• Molecular Formula: C₃₅H₃₆N₂O₇
• Molecular Weight: 596.68
• Mol file: 200926-86-9.mol

Synonyms:

Chemical Property of 1-(1-carboxylato-2-phenyl-3-benzoylpropyl)-3-(2',6'-dimethyl-3',5'-diethoxycarbonyl-1',4'-dihydro-4'-pyridyl)pyridinium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-(1-carboxylato-2-phenyl-3-benzoylpropyl)-3-(2',6'-dimethyl-3',5'-diethoxycarbonyl-1',4'-dihydro-4'-pyridyl)pyridinium

There total 3 articles about 1-(1-carboxylato-2-phenyl-3-benzoylpropyl)-3-(2',6'-dimethyl-3',5'-diethoxycarbonyl-1',4'-dihydro-4'-pyridyl)pyridinium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

benzalacetophenone (94-41-7) + 3',5'-bisethoxycarbonyl-1-ethoxycarbonylmethyl-2',6'-dimethyl-1',4'-dihydro-[3,4']bipyridinyl-1-ium bromide → 1-(1-carboxylato-2-phenyl-3-benzoylpropyl)-3-(2',6'-dimethyl-3',5'-diethoxycarbonyl-1',4'-dihydro-4'-pyridyl)pyridinium (200926-86-9)

Guidance literature:

With ethanol; sodium; for 2h;

DOI:10.1007/BF02256759

Reference yield: 85.0%

benzalacetophenone (94-41-7) + 1-carboxymethyl-2',6'-dimethyl-3',5'-bisethoxycarbonyl-1',4'-dihydro-[3,4']bipyridinyl-1-ium (200926-80-3) → 1-(1-carboxylato-2-phenyl-3-benzoylpropyl)-3-(2',6'-dimethyl-3',5'-diethoxycarbonyl-1',4'-dihydro-4'-pyridyl)pyridinium (200926-86-9)

Guidance literature:

With ethanol; sodium; for 2h;

DOI:10.1007/BF02256759

Reference yield:

diethyl 2,6-dimethyl-4-(3-pyridyl)-1,4-dihydropyridine-3,5-dicarboxylate (23125-30-6) → 1-(1-carboxylato-2-phenyl-3-benzoylpropyl)-3-(2',6'-dimethyl-3',5'-diethoxycarbonyl-1',4'-dihydro-4'-pyridyl)pyridinium (200926-86-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 88 percent / acetone / Heating

2: 86 percent / Na, EtOH / 2 h

With ethanol; sodium; In acetone;

DOI:10.1007/BF02256759

upstream raw materials:

benzalacetophenone

1-carboxymethyl-2',6'-dimethyl-3',5'-bisethoxycarbonyl-1',4'-dihydro-[3,4']bipyridinyl-1-ium

diethyl 2,6-dimethyl-4-(3-pyridyl)-1,4-dihydropyridine-3,5-dicarboxylate