Technology Process of C26H28O8
There total 7 articles about C26H28O8 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 5 steps
1: {1,3-bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene}(methyl)gold; C51H57F3NO5PS / toluene / 36 h / 25 °C / Inert atmosphere
2: 3-chloro-benzenecarboperoxoic acid; sodium phosphate dibasic dodecahydrate / 1,2-dichloro-ethane / 3 h / 20 - 50 °C
3: palladium 10% on activated carbon; hydrogen / ethyl acetate / 5 h / 20 °C / 760.05 Torr
4: borane-THF / tetrahydrofuran / 12 h / 0 - 20 °C
5: tetrabutyl ammonium fluoride; bis(dibenzylideneacetone)-palladium(0) / tetrahydrofuran / 12 h / 25 °C / Reflux
With
borane-THF; sodium phosphate dibasic dodecahydrate; {1,3-bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene}(methyl)gold; palladium 10% on activated carbon; C51H57F3NO5PS; tetrabutyl ammonium fluoride; hydrogen; 3-chloro-benzenecarboperoxoic acid; bis(dibenzylideneacetone)-palladium(0);
In
tetrahydrofuran; ethyl acetate; 1,2-dichloro-ethane; toluene;
1: |Mukaiyama Aldol Addition / 2: |Baeyer-Villiger Ketone Oxidation;
DOI:10.1002/chem.201300702
- Guidance literature:
-
Multi-step reaction with 3 steps
1: palladium 10% on activated carbon; hydrogen / ethyl acetate / 5 h / 20 °C / 760.05 Torr
2: borane-THF / tetrahydrofuran / 12 h / 0 - 20 °C
3: tetrabutyl ammonium fluoride; bis(dibenzylideneacetone)-palladium(0) / tetrahydrofuran / 12 h / 25 °C / Reflux
With
borane-THF; palladium 10% on activated carbon; tetrabutyl ammonium fluoride; hydrogen; bis(dibenzylideneacetone)-palladium(0);
In
tetrahydrofuran; ethyl acetate;
DOI:10.1002/chem.201300702
- Guidance literature:
-
Multi-step reaction with 2 steps
1: borane-THF / tetrahydrofuran / 12 h / 0 - 20 °C
2: tetrabutyl ammonium fluoride; bis(dibenzylideneacetone)-palladium(0) / tetrahydrofuran / 12 h / 25 °C / Reflux
With
borane-THF; tetrabutyl ammonium fluoride; bis(dibenzylideneacetone)-palladium(0);
In
tetrahydrofuran;
DOI:10.1002/chem.201300702