W(NC₆H₅)(CH₂Si(CH₃)3)4

Base Information

• Chemical Name: W(NC₆H₅)(CH₂Si(CH₃)3)4
• CAS No.: 83634-59-7
• Molecular Formula: C₂₂H₄₉NSi₄W
• Molecular Weight: 623.83
• Mol file: 83634-59-7.mol

Synonyms:

Chemical Property of W(NC₆H₅)(CH₂Si(CH₃)3)4

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of W(NC₆H₅)(CH₂Si(CH₃)3)4

There total 1 articles about W(NC₆H₅)(CH₂Si(CH₃)3)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

Cl4(OEt2)W(NPh) + (trimethylsilyl)methylmagnesium chloride (13170-43-9) → W(NC6H5)(CH2Si(CH3)3)4 (83634-59-7)

Guidance literature:

In diethyl ether; soln. of W complex in Et2O added to soln. of Mg compd. in Et2O under N2at -78°C, mixture warmed to room temp., stirred for 16 h; filtration, washing with Et2O, evapn. in vac., dissolving in Et2O, addn. of acetonitrile, standing at -30°C for 24 h, filtration,, washing with acetonitrile, drying in vac.; elem. anal.;

DOI:10.1021/ja00390a016

Reference yield:

W(NC6H5)(CH2Si(CH3)3)4 (83634-59-7) → W(NC6H5)(CH2Si(CH3)3)2(CHSi(CH3)3) (83634-60-0)

Guidance literature:

In toluene; soln. of W complex in toluene heated at 60°C for 5 h under N2; evapn. in vac.;

DOI:10.1021/ja00390a016

upstream raw materials:

(trimethylsilyl)methylmagnesium chloride

Downstream raw materials:

W(NC₆H₅)(CH₂Si(CH₃)3)2(CHSi(CH₃)3)