tetraphenylarsonium dicarbonyldichlororhodate(I)

Base Information

• Chemical Name: tetraphenylarsonium dicarbonyldichlororhodate(I)
• CAS No.: 13986-82-8
• Molecular Formula: C₂Cl₂O₂Rh*C₂₄H₂₀As
• Molecular Weight: 613.177

Synonyms:

Chemical Property of tetraphenylarsonium dicarbonyldichlororhodate(I)

Chemical Property:

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Technology Process of tetraphenylarsonium dicarbonyldichlororhodate(I)

There total 4 articles about tetraphenylarsonium dicarbonyldichlororhodate(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

rhodium(III) chloride trihydrate + tetraphenylarsonium chloride (507-28-8,14842-08-1) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → tetraphenylarsonium dicarbonyldichlororhodate(I) (13986-82-8,30193-19-2)

Guidance literature:

With water; In N,N-dimethyl-formamide; reagents except of (C6H5)4AsCl mixed in DMF, soln. heated under reflux (160°C), after 15 min (C6H5)4AsCl added, mixt. concd. in vacuo at 100°C, cooled to room temp.; HCl added dropwise, filtered, washed with HCl soln., dried in vacuo, elem. anal.;

DOI:10.1002/1099-0682(200109)2001:9<2327::AID-EJIC2327>3.0.CO;2-D

Reference yield: 72.0%

N-Methylformamide (123-39-7) + rhodium(III) chloride trihydrate + tetraphenylarsonium chloride (507-28-8,14842-08-1) → tetraphenylarsonium dicarbonyldichlororhodate(I) (13986-82-8,30193-19-2)

Guidance literature:

With water; In further solvent(s); at 180°C with N-methylformamide or 140°C product obtained with less than 10 min;

DOI:10.1002/1099-0682(200109)2001:9<2327::AID-EJIC2327>3.0.CO;2-D

Reference yield: 1.0%

N-formyldiethylamine (617-84-5) + rhodium(III) chloride trihydrate → tetraphenylarsonium dicarbonyldichlororhodate(I) (13986-82-8,30193-19-2) + [NH2(C2H5)2](1+)*[RhCl2(CO)2](1-)=[NH2(C2H5)2](RhCl2(CO)2) (248951-92-0)

Guidance literature:

In further solvent(s); using diethylformamide at 160°C in 30 min;

DOI:10.1002/1099-0682(200109)2001:9<2327::AID-EJIC2327>3.0.CO;2-D

upstream raw materials:

tetraphenylarsonium chloride

N,N-dimethyl-formamide

N-Methylformamide

N-formyldiethylamine

Downstream raw materials:

[Rh(Se₂C₂(CO₂CH₃)2)(CO)2]^(1-)*As(C₆H₅)4⁽¹⁺⁾=[Rh(Se₂C₂(CO₂CH₃)2)(CO)2][As(C₆H₅)4]

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