(Ni(HN(CH₂CH₂)2NCH₂CH₂NCHC₆H₃BrO))⁽¹⁺⁾*B(C₆H₅)4^(1-)=(Ni(HN(CH₂CH₂)2NCH₂CH₂NCHC₆H₃BrO))(B(C₆H₅)4)

Base Information

• Chemical Name: (Ni(HN(CH₂CH₂)2NCH₂CH₂NCHC₆H₃BrO))⁽¹⁺⁾*B(C₆H₅)4^(1-)=(Ni(HN(CH₂CH₂)2NCH₂CH₂NCHC₆H₃BrO))(B(C₆H₅)4)
• CAS No.: 639458-07-4
• Molecular Formula: C₁₃H₁₇BrN₃NiO*C₂₄H₂₀B
• Molecular Weight: 689.125
• Mol file: 639458-07-4.mol

Synonyms:

Chemical Property of (Ni(HN(CH₂CH₂)2NCH₂CH₂NCHC₆H₃BrO))⁽¹⁺⁾*B(C₆H₅)4^(1-)=(Ni(HN(CH₂CH₂)2NCH₂CH₂NCHC₆H₃BrO))(B(C₆H₅)4)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (Ni(HN(CH₂CH₂)2NCH₂CH₂NCHC₆H₃BrO))⁽¹⁺⁾*B(C₆H₅)4^(1-)=(Ni(HN(CH₂CH₂)2NCH₂CH₂NCHC₆H₃BrO))(B(C₆H₅)4)

There total 1 articles about (Ni(HN(CH₂CH₂)2NCH₂CH₂NCHC₆H₃BrO))⁽¹⁺⁾*B(C₆H₅)4^(1-)=(Ni(HN(CH₂CH₂)2NCH₂CH₂NCHC₆H₃BrO))(B(C₆H₅)4) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

nickel(II) perchlorate hexahydrate + 4-bromo-2-[(2-piperazin-1-yl-ethylimino)-methyl]phenol (639452-69-0) + sodium tetraphenyl borate (143-66-8) → (Ni(HN(CH2CH2)2NCH2CH2NCHC6H3BrO))(1+)*B(C6H5)4(1-)=(Ni(HN(CH2CH2)2NCH2CH2NCHC6H3BrO))(B(C6H5)4) (639458-07-4)

Guidance literature:

In methanol; to soln. ligand in MeOH soln. Ni(ClO4)2*6H2O in MeOH was added dropwise and refluxed for 1 h, NaBPh4 was added; hot soln. was filtered and kept at room temp. for several days, ppt. wasfiltered, washed with Et2O, dried in vac., and recrystd. from acetone-p etroleum ether; elem. anal.;

DOI:10.1021/ic0346174

upstream raw materials:

4-bromo-2-[(2-piperazin-1-yl-ethylimino)-methyl]phenol

sodium tetraphenyl borate