Triethyl(octyl)silane

Base Information

• Chemical Name: Triethyl(octyl)silane
• CAS No.: 10175-53-8
• Molecular Formula: C14H32Si
• Molecular Weight: 228.494
• DSSTox Substance ID: DTXSID60535621
• Nikkaji Number: J404.102J
• Wikidata: Q82409974
• Mol file: 10175-53-8.mol

Synonyms:TRIETHYL(OCTYL)SILANE;Triathyloctylsilan;triethyl-octyl-silane;10175-53-8;DTXSID60535621

Chemical Property of Triethyl(octyl)silane

Chemical Property:

• Vapor Pressure: 0.018mmHg at 25°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 10
• Exact Mass: 228.227327555
• Heavy Atom Count: 15
• Complexity: 119

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCC[Si](CC)(CC)CC

Technology Process of Triethyl(octyl)silane

There total 3 articles about Triethyl(octyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

triethylsilane (617-86-7) + oct-1-ene (111-66-0,25068-25-1) → 4-octene (592-99-4,7642-15-1,14850-23-8) + oct-3-ene (14850-22-7,14919-01-8,138663-42-0,592-98-3) + 2-octene (111-67-1) + 1-(triethylsilyl)octane (10175-53-8) + triethyl-1-octenyl-silane (24602-28-6) + Triethyl-(1-methyl-heptyl)-silane

Guidance literature:

With [RhCl(triphenylphosphine){P(OC₆H₄NMe)OC₆H₄NHMe}]; In toluene; at 75 ℃; for 5h; Temperature; Catalytic behavior; Glovebox; Inert atmosphere;

DOI:10.1016/j.ica.2017.04.065

Reference yield:

triethylsilane (617-86-7) + oct-1-ene (111-66-0,25068-25-1) → octane (111-65-9) + 1-(triethylsilyl)octane (10175-53-8) + (E)-1-triethylsilyl-1-octene (31930-43-5) + (Z)-triethyl(oct-1-en-1-yl)silane

Guidance literature:

With cis-dibromo(η2-dihydrogen)(nitrosyl)-trans-bis(triisopropylphosphane)rhenium; In ⁽²⁾H₈-toluene; at 110 ℃; for 24h; optical yield given as %de; chemoselective reaction; Inert atmosphere;

DOI:10.1002/chem.200802019

Reference yield:

triethylsilane (617-86-7) + oct-1-ene (111-66-0,25068-25-1) → octane (111-65-9) + 1-(triethylsilyl)octane (10175-53-8) + triethyl-1-octenyl-silane (24602-28-6) + Triethyl-(1-methyl-heptyl)-silane

Guidance literature:

With RuC₃*3H₂O; (3-bromophenyl)(diphenyl)phosphine; at 90 ℃; for 5h; Inert atmosphere;

DOI:10.1002/aoc.3092

upstream raw materials:

triethylsilane

oct-1-ene