Benzene, 1,1'-(1,6-hexanediyl)bis[4-bromo-

Base Information

• Chemical Name: Benzene, 1,1'-(1,6-hexanediyl)bis[4-bromo-
• CAS No.: 101783-96-4
• Molecular Formula: C18H20Br2
• Molecular Weight: 396.165
• DSSTox Substance ID: DTXSID00601910
• Nikkaji Number: J2.337.094H
• Wikidata: Q82498777
• Mol file: 101783-96-4.mol

Synonyms:101783-96-4;Benzene, 1,1'-(1,6-hexanediyl)bis[4-bromo-;1,6-Bis(4-bromophenyl)hexane;SCHEMBL134452;DTXSID00601910;1,1'-(Hexane-1,6-diyl)bis(4-bromobenzene);Benzene, 1,1''-(1,6-hexanediyl)bis[4-bromo-;1-BROMO-4-[6-(4-BROMOPHENYL)HEXYL]BENZENE

Chemical Property of Benzene, 1,1'-(1,6-hexanediyl)bis[4-bromo-

Chemical Property:

• XLogP3: 7.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 7
• Exact Mass: 395.99113
• Heavy Atom Count: 20
• Complexity: 212

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC=C1CCCCCCC2=CC=C(C=C2)Br)Br

Technology Process of Benzene, 1,1'-(1,6-hexanediyl)bis[4-bromo-

There total 4 articles about Benzene, 1,1'-(1,6-hexanediyl)bis[4-bromo- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

1,6-bis(4-bromophenyl)hexane-1,6-dione (101735-51-7) → 1,6-bis-(4-bromophenyl)hexane (101783-96-4)

Guidance literature:

With potassium hydroxide; hydrazine; In diethyl ether; 2,2'-[1,2-ethanediylbis(oxy)]bisethanol;

DOI:10.1016/j.tetlet.2006.05.107

Reference yield:

Adipic acid dichloride (111-50-2) → 1,6-bis-(4-bromophenyl)hexane (101783-96-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 66 percent / AlCl₃ / 3 h / 40 °C

2: 88 percent / NH₂NH₂; KOH / diethyl ether; triethylene glycol

With potassium hydroxide; aluminium trichloride; hydrazine; In diethyl ether; 2,2'-[1,2-ethanediylbis(oxy)]bisethanol; 1: Friedel-Crafts reaction / 2: Wolff-Kishner-Huang-Minlon reaction;

DOI:10.1016/j.tetlet.2006.05.107

Reference yield:

bromobenzene (108-86-1,52753-63-6) → 1,6-bis-(4-bromophenyl)hexane (101783-96-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 66 percent / AlCl₃ / 3 h / 40 °C

2: 88 percent / NH₂NH₂; KOH / diethyl ether; triethylene glycol

With potassium hydroxide; aluminium trichloride; hydrazine; In diethyl ether; 2,2'-[1,2-ethanediylbis(oxy)]bisethanol; 1: Friedel-Crafts reaction / 2: Wolff-Kishner-Huang-Minlon reaction;

DOI:10.1016/j.tetlet.2006.05.107

upstream raw materials:

1,6-bis(4-bromophenyl)hexane-1,6-dione

bromobenzene

Adipic acid dichloride

Downstream raw materials:

4,4'-hexanediyl-di-benzoic acid

1-(4-bromophenyl)-6-(4'-methoxyphen-4-yl)hexane

1,6-bis-(4-iodophenyl)hexane

1-(4-bromophenyl)-6-(4'hydroxybiphen-4-yl)hexane