Technology Process of (+)-(SS)-S-<(1Z,7E)-1,7,9-decatrienyl>-S-phenyl-N-(p-tolylsulphonyl)sulphoximine
There total 11 articles about (+)-(SS)-S-<(1Z,7E)-1,7,9-decatrienyl>-S-phenyl-N-(p-tolylsulphonyl)sulphoximine which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
n-butyllithium; potassium tert-butylate; diethyl chlorophosphate;
In
tetrahydrofuran; hexane;
Yield given. Yields of byproduct given;
1.) -78 deg C, 10 min; 2.) r.t., 30 min;
DOI:10.1016/0040-4020(95)00267-C
- Guidance literature:
-
Multi-step reaction with 9 steps
1: diisobutylaluminum hydride (DIBAL) / toluene / -78 °C
2: H+ / CH2Cl2 / Ambient temperature
3: CH2Cl2 / Ambient temperature
4: diisobutylaluminum hydride (DIBAL) / toluene / -78 °C
5: MnO2 / CH2Cl2
6: tetrahydrofuran
7: MeOH, H+
8: (COCl)2, DMSO / CH2Cl2 / -60 °C
9: tetrahydrofuran; hexane / 0.5 h / -5 °C
With
methanol; manganese(IV) oxide; oxalyl dichloride; hydrogen cation; diisobutylaluminium hydride; dimethyl sulfoxide;
In
tetrahydrofuran; hexane; dichloromethane; toluene;
DOI:10.1016/S0957-4166(00)80016-6
- Guidance literature:
-
Multi-step reaction with 8 steps
1: H+ / CH2Cl2 / Ambient temperature
2: CH2Cl2 / Ambient temperature
3: diisobutylaluminum hydride (DIBAL) / toluene / -78 °C
4: MnO2 / CH2Cl2
5: tetrahydrofuran
6: MeOH, H+
7: (COCl)2, DMSO / CH2Cl2 / -60 °C
8: tetrahydrofuran; hexane / 0.5 h / -5 °C
With
methanol; manganese(IV) oxide; oxalyl dichloride; hydrogen cation; diisobutylaluminium hydride; dimethyl sulfoxide;
In
tetrahydrofuran; hexane; dichloromethane; toluene;
DOI:10.1016/S0957-4166(00)80016-6
