2-Hexyl-6-[4'-((1Z,4Z,9Z,15Z)-2,8,12,18-tetrahexyl-3,7,13,17-tetramethyl-15-p-tolyl-porphyrin-5-yl)-biphenyl-4-ylmethyl]-pyrrolo[3,4-f]isoindole-1,3,5,7-tetraone

Base Information

• Chemical Name: 2-Hexyl-6-[4'-((1Z,4Z,9Z,15Z)-2,8,12,18-tetrahexyl-3,7,13,17-tetramethyl-15-p-tolyl-porphyrin-5-yl)-biphenyl-4-ylmethyl]-pyrrolo[3,4-f]isoindole-1,3,5,7-tetraone
• CAS No.: 138537-02-7
• Molecular Formula: C₈₄H₁₀₀N₆O₄
• Molecular Weight: 1257.76
• Mol file: 138537-02-7.mol

Synonyms:

Chemical Property of 2-Hexyl-6-[4'-((1Z,4Z,9Z,15Z)-2,8,12,18-tetrahexyl-3,7,13,17-tetramethyl-15-p-tolyl-porphyrin-5-yl)-biphenyl-4-ylmethyl]-pyrrolo[3,4-f]isoindole-1,3,5,7-tetraone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-Hexyl-6-[4'-((1Z,4Z,9Z,15Z)-2,8,12,18-tetrahexyl-3,7,13,17-tetramethyl-15-p-tolyl-porphyrin-5-yl)-biphenyl-4-ylmethyl]-pyrrolo[3,4-f]isoindole-1,3,5,7-tetraone

There total 8 articles about 2-Hexyl-6-[4'-((1Z,4Z,9Z,15Z)-2,8,12,18-tetrahexyl-3,7,13,17-tetramethyl-15-p-tolyl-porphyrin-5-yl)-biphenyl-4-ylmethyl]-pyrrolo[3,4-f]isoindole-1,3,5,7-tetraone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hexan-1-amine (111-26-2) → 2-Hexyl-6-[4'-((1Z,4Z,9Z,15Z)-2,8,12,18-tetrahexyl-3,7,13,17-tetramethyl-15-p-tolyl-porphyrin-5-yl)-biphenyl-4-ylmethyl]-pyrrolo[3,4-f]isoindole-1,3,5,7-tetraone (138537-02-7)

Guidance literature:

Multi-step reaction with 3 steps

1: dimethylformamide / Heating

2: trifluoroacetic acid, 5percent aqueous H₂SO₄ / CHCl₃ / Ambient temperature

3: 1.) trichloroacetic acid, 2.) p-chloranil / 1.) CH₃CN, 2.) THF

With sulfuric acid; chloranil; trifluoroacetic acid; trichloroacetic acid; In chloroform; N,N-dimethyl-formamide;

DOI:10.1246/bcsj.64.3005

Reference yield:

Pyromellitic dianhydride (89-32-7,34527-94-1) → 2-Hexyl-6-[4'-((1Z,4Z,9Z,15Z)-2,8,12,18-tetrahexyl-3,7,13,17-tetramethyl-15-p-tolyl-porphyrin-5-yl)-biphenyl-4-ylmethyl]-pyrrolo[3,4-f]isoindole-1,3,5,7-tetraone (138537-02-7)

Guidance literature:

Multi-step reaction with 3 steps

1: dimethylformamide / Heating

2: trifluoroacetic acid, 5percent aqueous H₂SO₄ / CHCl₃ / Ambient temperature

3: 1.) trichloroacetic acid, 2.) p-chloranil / 1.) CH₃CN, 2.) THF

With sulfuric acid; chloranil; trifluoroacetic acid; trichloroacetic acid; In chloroform; N,N-dimethyl-formamide;

DOI:10.1246/bcsj.64.3005

Reference yield:

[4'-(5,5-Dimethyl-[1,3]dioxan-2-yl)-biphenyl-4-yl]-methanol (152424-50-5) → 2-Hexyl-6-[4'-((1Z,4Z,9Z,15Z)-2,8,12,18-tetrahexyl-3,7,13,17-tetramethyl-15-p-tolyl-porphyrin-5-yl)-biphenyl-4-ylmethyl]-pyrrolo[3,4-f]isoindole-1,3,5,7-tetraone (138537-02-7)

Guidance literature:

Multi-step reaction with 6 steps

1: pyridinium chlorochromate, sodium acetate

2: 74 percent / hydroxylamine hydrochloride, sodium carbonate / ethanol; CH₂Cl₂; H₂O / Ambient temperature

3: 81 percent / LiAlH₄ / tetrahydrofuran / 6 h / 70 °C

4: dimethylformamide / Heating

5: trifluoroacetic acid, 5percent aqueous H₂SO₄ / CHCl₃ / Ambient temperature

6: 1.) trichloroacetic acid, 2.) p-chloranil / 1.) CH₃CN, 2.) THF

With lithium aluminium tetrahydride; sulfuric acid; hydroxylamine hydrochloride; sodium acetate; chloranil; sodium carbonate; pyridinium chlorochromate; trifluoroacetic acid; trichloroacetic acid; In tetrahydrofuran; ethanol; dichloromethane; chloroform; water; N,N-dimethyl-formamide;

DOI:10.1246/bcsj.64.3005

upstream raw materials:

4-methyl-benzaldehyde

N-hexyl-N'-<<4'-formyl-<1,1'-biphenyl>-4-yl>methyl>-1,2:4,5-benzenebis(dicarboximide)

bis(3-hexyl-4-methyl-2-pyrrolyl)methane

hexan-1-amine