[2,2-(CO)2-1,2-μ-(OC(4-C6H4CHO)NH)-closo-2,1,10-FeC2B7H8]

Base Information

• Chemical Name: [2,2-(CO)2-1,2-μ-(OC(4-C6H4CHO)NH)-closo-2,1,10-FeC2B7H8]
• CAS No.: 1227612-12-5
• Molecular Formula: C₁₂H₁₄B₇FeNO₄
• Molecular Weight: 367.771
• Mol file: 1227612-12-5.mol

Synonyms:

Chemical Property of [2,2-(CO)2-1,2-μ-(OC(4-C6H4CHO)NH)-closo-2,1,10-FeC2B7H8]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [2,2-(CO)2-1,2-μ-(OC(4-C6H4CHO)NH)-closo-2,1,10-FeC2B7H8]

There total 1 articles about [2,2-(CO)2-1,2-μ-(OC(4-C6H4CHO)NH)-closo-2,1,10-FeC2B7H8] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

[1-OH-2,2,2-(CO)3-closo-2,1,10-FeC2B7H8] (911221-88-0) + 4-cyanobenzaldehyde (105-07-7) → [2,2-(CO)2-1,2-μ-(OC(4-C6H4CHO)NH)-closo-2,1,10-FeC2B7H8] (1227612-12-5)

Guidance literature:

With Me₃NO; In dichloromethane; (N2); using Schlenk techniques; treatment of dichloromethane soln. of 1-OH-2,2,2-(CO)3-closo-2,1,10-FeC2B7H8 with p-OC(H)C6H4CN in the presence of Me3NO; stirring at ambient temp. for 18 h; removal of solvent under reduced pressure, dissolving in CH2Cl2-petroleum ether (4:1), chromy., removal of solvent, crystn.; elem. anal.;

DOI:10.1021/om900970x

upstream raw materials:

[1-OH-2,2,2-(CO)3-closo-2,1,10-FeC₂B₇H₈]

4-cyanobenzaldehyde