[Ru(C₃(4-methoxyphenyl)Me)(indenyl)(PPh₃)P(OC₁₀H₆)2N(CH₂Ph)2]PF₆

Base Information

• Chemical Name: [Ru(C₃(4-methoxyphenyl)Me)(indenyl)(PPh₃)P(OC₁₀H₆)2N(CH₂Ph)2]PF₆
• CAS No.: 1287687-05-1
• Molecular Formula: C₇₂H₅₈NO₃P₂Ru*F₆P
• Molecular Weight: 1293.24
• Mol file: 1287687-05-1.mol

Synonyms:

Chemical Property of [Ru(C₃(4-methoxyphenyl)Me)(indenyl)(PPh₃)P(OC₁₀H₆)2N(CH₂Ph)2]PF₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ru(C₃(4-methoxyphenyl)Me)(indenyl)(PPh₃)P(OC₁₀H₆)2N(CH₂Ph)2]PF₆

There total 1 articles about [Ru(C₃(4-methoxyphenyl)Me)(indenyl)(PPh₃)P(OC₁₀H₆)2N(CH₂Ph)2]PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

rac-2-(4-methoxyphenyl)but-3-yn-2-ol (15960-71-1) + [RuCl(indenyl)(PPh3)P(OC10H6)2N(CH2Ph)2] (1190481-97-0) + triethyloxonium hexaflourophosphate (17950-40-2) → [Ru(C3(4-methoxyphenyl)Me)(indenyl)(PPh3)P(OC10H6)2N(CH2Ph)2]PF6 (1287687-05-1)

Guidance literature:

In dichloromethane; CH2Cl2 added to Schlenk flask contg. Ru complex; cooled to 0°C; (EtO)3PF6 in CH2Cl2 added; after 1 h, butynol deriv. added; after 30 min cold bath removed. soln. warmed to room temp. over 30 min; solvent removed under vac.; washed with Et2O, dried under vac.; elem. anal.;

DOI:10.1002/ejic.201001176

upstream raw materials:

rac-2-(4-methoxyphenyl)but-3-yn-2-ol

[RuCl(indenyl)(PPh₃)P(OC₁₀H₆)2N(CH₂Ph)2]

triethyloxonium hexaflourophosphate

Refernces