benzyl 2,3-di-O-benzyl-6-deoxy-6-[2,3,5-tri-O-benzyl-1,4-dideoxy-1,4-episulfoniumylidene-D-arabinitol]-4-O-sulfoxy-β-D-glucopyranose inner salt

Base Information

Chemical Name:benzyl 2,3-di-O-benzyl-6-deoxy-6-[2,3,5-tri-O-benzyl-1,4-dideoxy-1,4-episulfoniumylidene-D-arabinitol]-4-O-sulfoxy-β-D-glucopyranose inner salt
CAS No.:878288-85-8
Molecular Formula:C₅₃H₅₆O₁₁S₂
Molecular Weight:933.153
Hs Code.:

benzyl 2,3-di-O-benzyl-6-deoxy-6-[2,3,5-tri-O-benzyl-1,4-dideoxy-1,4-episulfoniumylidene-D-arabinitol]-4-O-sulfoxy-β-D-glucopyranose inner salt

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Chemical Property of benzyl 2,3-di-O-benzyl-6-deoxy-6-[2,3,5-tri-O-benzyl-1,4-dideoxy-1,4-episulfoniumylidene-D-arabinitol]-4-O-sulfoxy-β-D-glucopyranose inner salt

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Technology Process of benzyl 2,3-di-O-benzyl-6-deoxy-6-[2,3,5-tri-O-benzyl-1,4-dideoxy-1,4-episulfoniumylidene-D-arabinitol]-4-O-sulfoxy-β-D-glucopyranose inner salt

There total 3 articles about benzyl 2,3-di-O-benzyl-6-deoxy-6-[2,3,5-tri-O-benzyl-1,4-dideoxy-1,4-episulfoniumylidene-D-arabinitol]-4-O-sulfoxy-β-D-glucopyranose inner salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.0%

: 878288-78-9
benzyl 2,3-di-O-benzyl-β-D-glucopyranoside-4,6-cyclic sulfate

: 187590-77-8
1,4-anhydro-2,3,5-tri-O-benzyl-4-thio-D-arabinitol

: 878288-85-8
benzyl 2,3-di-O-benzyl-6-deoxy-6-[2,3,5-tri-O-benzyl-1,4-dideoxy-1,4-episulfoniumylidene-D-arabinitol]-4-O-sulfoxy-β-D-glucopyranose inner salt

: C₅₃H₅₆O₁₁S₂

Guidance literature:: With 1,1,1,3',3',3'-hexafluoro-propanol; at 70 ℃; for 42h;
DOI:10.1021/jo052252u

Reference yield:

: 913534-93-7
(4aR,6R,7R,8R,8aR)-6,7,8-Tris-benzyloxy-hexahydro-pyrano[3,2-d][1,3,2]dioxathiine 2-oxide

: 878288-85-8
benzyl 2,3-di-O-benzyl-6-deoxy-6-[2,3,5-tri-O-benzyl-1,4-dideoxy-1,4-episulfoniumylidene-D-arabinitol]-4-O-sulfoxy-β-D-glucopyranose inner salt

Guidance literature:: Multi-step reaction with 2 steps

1: 1.48 g / sodium periodate; RuCl₃*H₂O / acetonitrile; CCl₄; H₂O / 0.25 h / 20 °C

2: 31 percent / 1,1,1,3,3,3-hexafluoro-2-propanol / 42 h / 70 °C

With ruthenium trichloride; sodium periodate; 1,1,1,3',3',3'-hexafluoro-propanol; In tetrachloromethane; water; acetonitrile;
DOI:10.1021/jo052252u

Reference yield:

: 67831-41-8
benzyl 2,3-di-O-benzyl-β-D-glucopyranoside

: 878288-85-8
benzyl 2,3-di-O-benzyl-6-deoxy-6-[2,3,5-tri-O-benzyl-1,4-dideoxy-1,4-episulfoniumylidene-D-arabinitol]-4-O-sulfoxy-β-D-glucopyranose inner salt

Guidance literature:: Multi-step reaction with 3 steps

1: 1.57 g / thionyl chloride; triethylamine / CH₂Cl₂ / 0.33 h / 20 °C

2: 1.48 g / sodium periodate; RuCl₃*H₂O / acetonitrile; CCl₄; H₂O / 0.25 h / 20 °C

3: 31 percent / 1,1,1,3,3,3-hexafluoro-2-propanol / 42 h / 70 °C

With ruthenium trichloride; sodium periodate; thionyl chloride; 1,1,1,3',3',3'-hexafluoro-propanol; triethylamine; In tetrachloromethane; dichloromethane; water; acetonitrile;
DOI:10.1021/jo052252u