tert-butyldipenylsilanyl (R)-3-(tert-butyldiphenylsilanyloxy)-2-((2Z,6E,13E)-3,8,8,14,18-pentamethyl-11-methylene-nonadeca-2,6,13,17-tetraenyloxy)-propanoate

Base Information

Chemical Name:tert-butyldipenylsilanyl (R)-3-(tert-butyldiphenylsilanyloxy)-2-((2Z,6E,13E)-3,8,8,14,18-pentamethyl-11-methylene-nonadeca-2,6,13,17-tetraenyloxy)-propanoate
CAS No.:145012-55-1
Molecular Formula:C₆₀H₈₂O₄Si₂
Molecular Weight:923.48
Hs Code.:

tert-butyldipenylsilanyl (R)-3-(tert-butyldiphenylsilanyloxy)-2-((2Z,6E,13E)-3,8,8,14,18-pentamethyl-11-methylene-nonadeca-2,6,13,17-tetraenyloxy)-propanoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of tert-butyldipenylsilanyl (R)-3-(tert-butyldiphenylsilanyloxy)-2-((2Z,6E,13E)-3,8,8,14,18-pentamethyl-11-methylene-nonadeca-2,6,13,17-tetraenyloxy)-propanoate

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Technology Process of tert-butyldipenylsilanyl (R)-3-(tert-butyldiphenylsilanyloxy)-2-((2Z,6E,13E)-3,8,8,14,18-pentamethyl-11-methylene-nonadeca-2,6,13,17-tetraenyloxy)-propanoate

There total 1 articles about tert-butyldipenylsilanyl (R)-3-(tert-butyldiphenylsilanyloxy)-2-((2Z,6E,13E)-3,8,8,14,18-pentamethyl-11-methylene-nonadeca-2,6,13,17-tetraenyloxy)-propanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (R)-3-hydroxy-2-<(2Z,6E,13E)-3,8,8,14,18-pentamethyl-11-methylene-nonadeca-2,6,13,17-tetraene-1-yloxy>-propanoic acid

: 58479-61-1
tert-butylchlorodiphenylsilane

: 145012-55-1
tert-butyldipenylsilanyl (R)-3-(tert-butyldiphenylsilanyloxy)-2-((2Z,6E,13E)-3,8,8,14,18-pentamethyl-11-methylene-nonadeca-2,6,13,17-tetraenyloxy)-propanoate

Guidance literature:: With dmap; triethylamine; In dichloromethane; at 20 ℃; for 21h;
DOI:10.1016/S0040-4020(01)86589-3

Reference yield:

: 145012-55-1
tert-butyldipenylsilanyl (R)-3-(tert-butyldiphenylsilanyloxy)-2-((2Z,6E,13E)-3,8,8,14,18-pentamethyl-11-methylene-nonadeca-2,6,13,17-tetraenyloxy)-propanoate

: 145012-58-4
(S)-3-(tert-butyldiphenylsilanyloxy)-2-((2Z,6E,13E)-3,8,8,14,18-pentamethyl-11-methylene-nonadeca-2,6,13,17-tetraenyloxy)-propanol

Guidance literature:: With diisobutylaluminium hydride; In dichloromethane; toluene; 1) 0 deg C, 1 h, 2) 20 deg C, 2 h;
DOI:10.1016/S0040-4020(01)86589-3

Reference yield:

: 145012-55-1
tert-butyldipenylsilanyl (R)-3-(tert-butyldiphenylsilanyloxy)-2-((2Z,6E,13E)-3,8,8,14,18-pentamethyl-11-methylene-nonadeca-2,6,13,17-tetraenyloxy)-propanoate

: (5S)-5-(tert-butyldiphenylsilanyloxy-methyl)-1,4-dioxan-2ax-yl (1S)-camphanoate

Guidance literature:: Multi-step reaction with 3 steps

1: 432.1 mg / DIBAH / CH₂Cl₂; toluene / 1) 0 deg C, 1 h, 2) 20 deg C, 2 h

2: 1) O₃, MeOH, 2) NaBH₄ / 1) CH₂Cl₂, -78 deg C, 10 min 2) CH₃OH, -78 deg C to 20 C, 2 h

3: 16.3 mg / pyridine / 2 h / 20 °C

With pyridine; methanol; sodium tetrahydroborate; diisobutylaluminium hydride; ozone; In dichloromethane; toluene;
DOI:10.1016/S0040-4020(01)86589-3