(R,R)-2--6-hexanolide

Base Information

Chemical Name:(R*,R*)-2--6-hexanolide
CAS No.:139367-42-3
Molecular Formula:C₁₆H₂₄O₃Si
Molecular Weight:292.45
Hs Code.:

(R*,R*)-2-<hydroxy(2-trimethylsilylphenyl)methyl>-6-hexanolide

Synonyms:

Suppliers and Price of (R*,R*)-2--6-hexanolide

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (R*,R*)-2--6-hexanolide

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of (R*,R*)-2--6-hexanolide

There total 6 articles about (R*,R*)-2--6-hexanolide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 17887-55-7
2-trimethylsilylbenzaldehyde

: 87532-05-6
trimethyl[(4,5,6,7-tetrahydro-2-oxepinyl)oxy]silane

: 139367-42-3,139367-52-5
(R*,S*)-2--6-hexanolide

: 139367-42-3,139367-52-5
(R*,R*)-2--6-hexanolide

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; at -78 ℃; Yield given. Yields of byproduct given;
DOI:10.1248/cpb.39.2863

Reference yield:

: 17887-55-7
2-trimethylsilylbenzaldehyde

: 87532-05-6
trimethyl[(4,5,6,7-tetrahydro-2-oxepinyl)oxy]silane

: 139367-42-3,139367-52-5
(R*,S*)-2--6-hexanolide

: 139367-42-3,139367-52-5
(R*,R*)-2--6-hexanolide

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; at -78 ℃; Yield given. Yields of byproduct given;
DOI:10.1248/cpb.39.2863

Reference yield:

: 87532-05-6
trimethyl[(4,5,6,7-tetrahydro-2-oxepinyl)oxy]silane

: 139367-42-3,139367-52-5
(R*,S*)-2--6-hexanolide

: 139367-42-3,139367-52-5
(R*,R*)-2--6-hexanolide

Guidance literature:: With (Sp)-tricarbonyl[η6-2-(trimethylsilyl)benzaldehyde]chromium(0); boron trifluoride diethyl etherate; In dichloromethane; at -78 ℃; Mechanism; high erythro selectivity; aldol reaction of free aldehydes; other substrates;
DOI:10.1248/cpb.39.2863