{[(16,16,17,17,18,18,18-Heptafluorooctadecyl)oxy]methyl}benzene

Base Information

Chemical Name:{[(16,16,17,17,18,18,18-Heptafluorooctadecyl)oxy]methyl}benzene
CAS No.:102197-77-3
Molecular Formula:C25H37F7O
Molecular Weight:486.557
Hs Code.:
DSSTox Substance ID:DTXSID70543939
Wikidata:Q82420910
Mol file:102197-77-3.mol

Synonyms:102197-77-3;{[(16,16,17,17,18,18,18-HEPTAFLUOROOCTADECYL)OXY]METHYL}BENZENE;(((16,16,17,17,18,18,18-Heptafluorooctadecyl)oxy)methyl)benzene;DTXSID70543939

Suppliers and Price of {[(16,16,17,17,18,18,18-Heptafluorooctadecyl)oxy]methyl}benzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of {[(16,16,17,17,18,18,18-Heptafluorooctadecyl)oxy]methyl}benzene

Chemical Property:

XLogP3:10.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:8
Rotatable Bond Count:19
Exact Mass:486.27326293
Heavy Atom Count:33
Complexity:474

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)COCCCCCCCCCCCCCCCC(C(C(F)(F)F)(F)F)(F)F

Technology Process of {[(16,16,17,17,18,18,18-Heptafluorooctadecyl)oxy]methyl}benzene

There total 5 articles about {[(16,16,17,17,18,18,18-Heptafluorooctadecyl)oxy]methyl}benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 5-benzyloxy-pentylmagnesium bromide

: 102197-76-2
1-bromo-11,11,12,12,13,13,13-heptafluorotridecane

: 102197-77-3
1-benzyloxy-16,16,17,17,18,18,18-heptafluorooctadecane

Guidance literature:: dilithium tetrachlorocuprate; In tetrahydrofuran;
DOI:10.1248/cpb.35.647

Reference yield:

: 50816-18-7
9-decen-1-yl acetate

: 102197-77-3
1-benzyloxy-16,16,17,17,18,18,18-heptafluorooctadecane

Guidance literature:: Multi-step reaction with 5 steps

1: Fe₃(CO)12 / 5.5 h / 80 °C

2: Zn powder / acetic acid; diethyl ether / 1 h / Ambient temperature

3: 5 percent methanolic KOH / 2 h / Ambient temperature

4: 85 percent / triphenylphosphine dibromide / dimethylformamide; acetonitrile

5: 85 percent / 0.1 M Li₂CuCl₄ / tetrahydrofuran

With potassium hydroxide; zinc; dibromotriphenylphosphorane; dilithium tetrachlorocuprate; triiron dodecarbonyl; In tetrahydrofuran; diethyl ether; acetic acid; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1248/cpb.35.647

Reference yield:

: 102197-75-1
11,11,12,12,13,13,13-heptafluorotridecan-1-ol

: 102197-77-3
1-benzyloxy-16,16,17,17,18,18,18-heptafluorooctadecane

Guidance literature:: Multi-step reaction with 2 steps

1: 85 percent / triphenylphosphine dibromide / dimethylformamide; acetonitrile

2: 85 percent / 0.1 M Li₂CuCl₄ / tetrahydrofuran

With dibromotriphenylphosphorane; dilithium tetrachlorocuprate; In tetrahydrofuran; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1248/cpb.35.647