C₃₇H₄₆O₃Si

Base Information

Chemical Name:C₃₇H₄₆O₃Si
CAS No.:1384122-65-9
Molecular Formula:C₃₇H₄₆O₃Si
Molecular Weight:566.856
Hs Code.:

C<sub>37</sub>H<sub>46</sub>O<sub>3</sub>Si

Synonyms:

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Chemical Property of C₃₇H₄₆O₃Si

Chemical Property:

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Technology Process of C₃₇H₄₆O₃Si

There total 14 articles about C₃₇H₄₆O₃Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₄₃H₆₀O₃Si₂

: 1229041-62-6
(3S,7aS)-3a-(3-(tert-butyldiphenylsilyloxy)propyl)-6-methyl-2-methylene-3-(phenoxymethyl)hexahydro-1H-inden-4(2H)-one

: 1384122-65-9
C₃₇H₄₆O₃Si

Guidance literature:: With silver hexafluoroantimonate; (triphenylphosphine)gold(I) chloride; In dichloromethane; isopropyl alcohol; at 23 ℃; Reagent/catalyst; Overall yield = 94 %; Inert atmosphere;
DOI:10.1021/jo300872y

Reference yield:

: 56487-70-8
(3aS,6aR)-3,3a,4,6a-tetrahydro-2H-cyclopenta[b]furan-2-one

: 1384122-65-9
C₃₇H₄₆O₃Si

Guidance literature:: Multi-step reaction with 9 steps

1.1: copper(I) bromide dimethylsulfide complex; dimethylsulfide / tetrahydrofuran / -20 °C / Inert atmosphere

1.2: Inert atmosphere

2.1: lithium aluminium tetrahydride / tetrahydrofuran / Reflux; Inert atmosphere

3.1: 2,6-dimethylpyridine / dichloromethane / -78 °C / Inert atmosphere

4.1: Dess-Martin periodane / dichloromethane / Inert atmosphere

5.1: sec.-butyllithium / tetrahydrofuran / 0.25 h / -78 °C / Inert atmosphere

5.2: 0.5 h / -78 °C / Inert atmosphere

5.3: 12 h / -78 - 23 °C / Inert atmosphere

6.1: 2,6-dimethylpyridine / dichloromethane / 0 °C / Inert atmosphere

7.1: oxalyl dichloride; dimethyl sulfoxide; triethylamine / dichloromethane / -78 - 23 °C / Inert atmosphere

8.1: potassium carbonate / methanol / Inert atmosphere

9.1: (triphenylphosphine)gold(I) chloride; silver hexafluoroantimonate / dichloromethane; isopropyl alcohol / 23 °C / Inert atmosphere

With 2,6-dimethylpyridine; silver hexafluoroantimonate; lithium aluminium tetrahydride; oxalyl dichloride; copper(I) bromide dimethylsulfide complex; (triphenylphosphine)gold(I) chloride; dimethylsulfide; sec.-butyllithium; potassium carbonate; Dess-Martin periodane; dimethyl sulfoxide; triethylamine; In tetrahydrofuran; methanol; dichloromethane; isopropyl alcohol; 7.1: |Swern Oxidation;
DOI:10.1021/jo300872y

Reference yield:

: 158478-17-2
Methyl 6-(tert-butyldiphenylsiloxy)-2-hexynoate

: 1229041-62-6
(3S,7aS)-3a-(3-(tert-butyldiphenylsilyloxy)propyl)-6-methyl-2-methylene-3-(phenoxymethyl)hexahydro-1H-inden-4(2H)-one

: 1384122-65-9
C₃₇H₄₆O₃Si

Guidance literature:: Multi-step reaction with 9 steps

1.1: copper(I) bromide dimethylsulfide complex; lithium diisopropyl amide / Inert atmosphere

2.1: diisobutylaluminium hydride / dichloromethane / Inert atmosphere

3.1: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran; dichloromethane / Inert atmosphere

4.1: iodine / dichloromethane / Inert atmosphere

5.1: sec.-butyllithium / tetrahydrofuran / 0.25 h / -78 °C / Inert atmosphere

5.2: 0.5 h / -78 °C / Inert atmosphere

5.3: 12 h / -78 - 23 °C / Inert atmosphere

6.1: 2,6-dimethylpyridine / dichloromethane / 0 °C / Inert atmosphere

7.1: oxalyl dichloride; dimethyl sulfoxide; triethylamine / dichloromethane / -78 - 23 °C / Inert atmosphere

8.1: potassium carbonate / methanol / Inert atmosphere

9.1: (triphenylphosphine)gold(I) chloride; silver hexafluoroantimonate / dichloromethane; isopropyl alcohol / 23 °C / Inert atmosphere

With 2,6-dimethylpyridine; silver hexafluoroantimonate; oxalyl dichloride; copper(I) bromide dimethylsulfide complex; (triphenylphosphine)gold(I) chloride; di-isopropyl azodicarboxylate; iodine; sec.-butyllithium; diisobutylaluminium hydride; potassium carbonate; dimethyl sulfoxide; triethylamine; triphenylphosphine; lithium diisopropyl amide; In tetrahydrofuran; methanol; dichloromethane; isopropyl alcohol; 3.1: |Mitsunobu Displacement / 7.1: |Swern Oxidation;
DOI:10.1021/jo300872y