hexakis(2,4,6-trimethylphenyl)digermatrisila[1.1.1]propellane

Base Information

Chemical Name:hexakis(2,4,6-trimethylphenyl)digermatrisila[1.1.1]propellane
CAS No.:1278408-94-8
Molecular Formula:C₅₄H₆₆Ge₂Si₃
Molecular Weight:944.555
Hs Code.:

Synonyms:

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Chemical Property of hexakis(2,4,6-trimethylphenyl)digermatrisila[1.1.1]propellane

Chemical Property:

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Technology Process of hexakis(2,4,6-trimethylphenyl)digermatrisila[1.1.1]propellane

There total 1 articles about hexakis(2,4,6-trimethylphenyl)digermatrisila[1.1.1]propellane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 4.0%

: germanium(II) chloride dioxane

: 5599-27-9
dichloro(dimesityl)silane

: 1278408-94-8
hexakis(2,4,6-trimethylphenyl)digermatrisila[1.1.1]propellane

Guidance literature:: With lithium naphthalene; In tetrahydrofuran; byproducts: LiCl, naphthalene; under Ar; freshly prepd. soln. of Li naphthalene in THF added dropwise to soln. of Si compd. and GeCl2*(dioxane) in THF at -78°C under stirring; mixt. stirred at -78°C for 1 h and at room temp. overnight; solvent and naphthalene removed at 60°C under vac.; residue extd.with hexane; extract concd.; column chromy. (silica gel, hexane-toluene (gradient)); crystn. from toluene soln. by layering with MeCN; crystals washed with acetone; elem. anal.;
DOI:10.1021/om100977z

Reference yield: 89.0%

: diferrocenyldisulfide

: 1278408-94-8
hexakis(2,4,6-trimethylphenyl)digermatrisila[1.1.1]propellane

: 108-88-3,15644-74-3,16713-13-6
toluene

: ferrocenyl-S-Ge(Si(2,4,6-trimethylphenyl)2)3Ge-S-ferrocenyl*1.39(toluene)

Guidance literature:: In tetrahydrofuran; under Ar; soln. of Ge compd. and Fe complex in THF stirred at room temp.for 1 wk; evapn. under vac.; residue dissolved in min. amt. of toluene; layered with MeCN; crystals sepd. and washed with acetone; elem. anal.;
DOI:10.1021/om100977z

Reference yield:

: diferrocenyldisulfide

: 1278408-94-8
hexakis(2,4,6-trimethylphenyl)digermatrisila[1.1.1]propellane

: ferrocenyl-S-Ge(Si(2,4,6-trimethylphenyl)2)3Ge-S-ferrocenyl

Guidance literature:: In benzene-d6; Irradiation (UV/VIS); under Ar; C6D6 added to mixt. of Ge compd. and Fe complex (molar ratio 1:1); sealed; exposed to daylight; not isolated, detected by (1)H NMR spectroscopy; Kinetics;
DOI:10.1021/om100977z