cis-(Ru(dppm)2(CH₃CN)Cl)(PF₆)

Base Information

• Chemical Name: cis-(Ru(dppm)2(CH₃CN)Cl)(PF₆)
• CAS No.: 79953-54-1
• Molecular Formula: C₅₂H₄₇ClNP₄Ru*F₆P
• Molecular Weight: 1091.33

Synonyms:

Chemical Property of cis-(Ru(dppm)2(CH₃CN)Cl)(PF₆)

Chemical Property:

Purity/Quality:

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Technology Process of cis-(Ru(dppm)2(CH₃CN)Cl)(PF₆)

There total 2 articles about cis-(Ru(dppm)2(CH₃CN)Cl)(PF₆) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

ammonium hexafluorophosphate + cis-dichlorodi[bis(diphenylphosphino)methane]ruthenium(II) + acetonitrile (75-05-8,26809-02-9) → cis-(Ru(dppm)2(CH3CN)Cl)(PF6) (79953-54-1)

Guidance literature:

In water; acetonitrile; cis-Ru(dppm)2Cl2 in 1:1 mixt. CH3CN-H2O stirred at room temp. for 30 min, added saturated NH4PF6 soln. followed by H2O; soln. volume reduced, solid filtered, washed with H2O followed by Et2O and air-dried; elem. anal.;

DOI:10.1021/ic00133a033

Reference yield:

sodium hexaflorophosphate + cis-[RuCl2(dppm)2] + acetonitrile (75-05-8,26809-02-9) → cis-(Ru(dppm)2(CH3CN)Cl)(PF6) (79953-54-1)

Guidance literature:

In acetonitrile; CH3CN added to mixt. of Ru complex and NaPF6, suspn. stirred for 2 h; filtered, solvent removed in vac., solid extd. with CH2Cl2, solvent evapd. in vac.; elem. anal.;

DOI:10.1002/(SICI)1521-3749(200005)626:5<1196::AID-ZAAC1196>3.0.CO;2-B

Reference yield: 97.5%

cis-(Ru(dppm)2(CH3CN)Cl)(PF6) (79953-54-1) + tert-butylisonitrile (119072-55-8,7188-38-7) → cis-(Ru(dppm)2Cl(CNtBu))PF6

Guidance literature:

In dichloromethane; Ru comlex dissolved in CH2Cl2, soln. immersed into ice-bath for 25 min,then tBuNC added, stirred for 30 min; solvent removed in vac., washed with ether and hexanes, dried in vac. at +4°C; elem. anal.;

DOI:10.1002/(SICI)1521-3749(200005)626:5<1196::AID-ZAAC1196>3.0.CO;2-B

upstream raw materials:

acetonitrile

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