cis-[Ru(4,4’-Ph₂-bpy)₂Cl₂]

Base Information

• Chemical Name: cis-[Ru(4,4’-Ph₂-bpy)₂Cl₂]
• CAS No.: 131681-29-3
• Molecular Formula: C₄₄H₃₂Cl₂N₄Ru
• Molecular Weight: 788.741

Synonyms:

Chemical Property of cis-[Ru(4,4’-Ph₂-bpy)₂Cl₂]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-[Ru(4,4’-Ph₂-bpy)₂Cl₂]

There total 1 articles about cis-[Ru(4,4’-Ph₂-bpy)₂Cl₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(η4-1,5-cyclooctadiene)dichlororuthenium(II) + 4,4'-diphenyl-2,2'-bipyridine (6153-92-0) → cis-[Ru(4,4’-Ph2-bpy)2Cl2] (131681-29-3,288399-10-0)

Guidance literature:

In 1,2-dichloro-benzene; at 140 ℃; for 3h; Inert atmosphere;

DOI:10.1021/jacs.8b10950

Reference yield: 67.0%

ammonium hexafluorophosphate + cis-[Ru(4,4’-Ph2-bpy)2Cl2] (131681-29-3,288399-10-0) + dipyrido[3,2-a:2’,3’-c]phenazin-11-amine (263155-54-0) → [Ru(4,4'-diphenyl-2,2'-bipyridine)2(7-amino-dipyrido[3,2-a:2',3'-c]phenazine][PF6]2

Guidance literature:

In 2-methoxy-ethanol; a mixt. of Ru-contg. compd. (0.104 mmol) and a ligand (0.111 mmol) in 2-methoxyethanol was refluxed for 5 h; the mixt. was cooled to room temp. and excess aq. NH4PF6 was added; the ppt. was collected by filtration on celite, washed with water and diethyl ether, and re-dissolved with CH3CN; the filtrate was evapd. and the residue dried in vac.; purifn. by TLC on silica with CH3CN-aq. KNO3 (10:1) as eluent;

DOI:10.1039/b211225f

Reference yield: 40.0%

ammonium hexafluorophosphate + cis-[Ru(4,4’-Ph2-bpy)2Cl2] (131681-29-3,288399-10-0) + 7-(4-tert-butylbenzoylamino)dipyrido[3,2-a:2',3'-c]phenazine (263155-56-2) → [Ru(4,4'-diphenyl-2,2'-bipyridine)2(dppz-NHCO-Ph-Bu(t))][PF6]2

Guidance literature:

In ethanol; water; a mixt. of Ru-contg. compd. (0.109 mmol) and a ligand (0.111 mmol) in de-aerated EtOH-H2O (1:1) was refluxed for 5 h; the mixt. was cooled to room temp., EtOH was evapd. from the soln. to which excess aq. NH4PF6 was added; the ppt. was collected by filtration on celite, washed with H2O and diethyl ether, and re-dissolved with CH3CN; filtrate was evapd. and the residue dried in vac.; purifn. by column chromy. on silica with CH3CN-aq. KNO3 (9:1) as eluent; crystn. from EtOH;

DOI:10.1039/b211225f

upstream raw materials:

4,4'-diphenyl-2,2'-bipyridine

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 131681-29-3 cis-[Ru(4,4’-Ph₂-bpy)₂Cl₂]

Send

Send

Metric Ton KG G Pound L ML

Send

Send