trans-bis[1,2-bis(diphenylphosphino)ethane]chloro(t-butylisocyanide)rhenium(I)-tetrahydrofuran (1/1)

Base Information

• Chemical Name: trans-bis[1,2-bis(diphenylphosphino)ethane]chloro(t-butylisocyanide)rhenium(I)-tetrahydrofuran (1/1)
• CAS No.: 97477-12-8
• Molecular Formula: C₄H₈O*C₅₇H₅₇ClNP₄Re
• Molecular Weight: 1173.75

Synonyms:

Chemical Property of trans-bis[1,2-bis(diphenylphosphino)ethane]chloro(t-butylisocyanide)rhenium(I)-tetrahydrofuran (1/1)

Chemical Property:

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Technology Process of trans-bis[1,2-bis(diphenylphosphino)ethane]chloro(t-butylisocyanide)rhenium(I)-tetrahydrofuran (1/1)

There total 1 articles about trans-bis[1,2-bis(diphenylphosphino)ethane]chloro(t-butylisocyanide)rhenium(I)-tetrahydrofuran (1/1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

trans-[ReCl(N2)(dppe)2] + tert-butylisonitrile (119072-55-8,7188-38-7) → trans-bis[1,2-bis(diphenylphosphino)ethane]chloro(t-butylisocyanide)rhenium(I)-tetrahydrofuran (1/1) (97477-12-8)

Guidance literature:

With THF; In tetrahydrofuran; under Ar mixt. was refluxed for 1 d, then for 4 d; soln. was concd., pentane was added with heating, filtered, complex sepd. on cooling to ca. 0°C, solid was washed with thf-pentane, dried in vac.; elem. anal.;

DOI:10.1039/DT9810001629

Reference yield: 42.0%

tetrafluoroboric acid + trans-bis[1,2-bis(diphenylphosphino)ethane]chloro(t-butylisocyanide)rhenium(I)-tetrahydrofuran (1/1) (97477-12-8) → trans-bis[1,2-bis(diphenylphosphino)ethane]chloro(t-butylaminocarbyne)rhenium tetrafluoroborate*CH2Cl2

Guidance literature:

In diethyl ether; benzene; mixt. was stirred for ca. 60 h; soln. was taken to dryness and the solid was crystd. from CH2Cl2-Et2O; elem. anal.;

DOI:10.1039/DT9810001629

upstream raw materials:

tert-butylisonitrile

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