((CO)3Cr)2(C₆H₅CH₂)4C₄B₈H₈

Base Information

Chemical Name:((CO)3Cr)2(C₆H₅CH₂)4C₄B₈H₈
CAS No.:110015-89-9
Molecular Formula:C₃₈H₃₆B₈Cr₂O₆
Molecular Weight:779.18
Hs Code.:

((CO)3Cr)2(C<sub>6</sub>H<sub>5</sub>CH<sub>2</sub>)4C<sub>4</sub>B<sub>8</sub>H<sub>8</sub>

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Chemical Property of ((CO)3Cr)2(C₆H₅CH₂)4C₄B₈H₈

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Technology Process of ((CO)3Cr)2(C₆H₅CH₂)4C₄B₈H₈

There total 5 articles about ((CO)3Cr)2(C₆H₅CH₂)4C₄B₈H₈ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 21.0%

: 105472-95-5
(C₆H₅CH₂)4C₄B₈H₈

: 199620-14-9,13007-92-6
chromium⁽⁰⁾ hexacarbonyl

: 110015-89-9,110026-54-5
((CO)3Cr)2(C₆H₅CH₂)4C₄B₈H₈

: 110026-54-5,110015-89-9
((CO)3Cr)2(C₆H₅CH₂)4C₄B₈H₈

Guidance literature:: In tetrahydrofuran; dibutyl ether; a mixt. of the carborane, Cr(CO)6, anhyd. Bu2O and THF was refluxed under dry N2 for 18 h; cooled to room temp., solvent was removed in vacuo, residue was dissolved in CH2Cl2 and chromd. on a SiO2 column (eluent CH2Cl2-hexane) to give an isomer mixt. which was sepd. by TLC on SiO2;

Reference yield: 21.0%

: 105472-95-5
(C₆H₅CH₂)4C₄B₈H₈

: 199620-14-9,13007-92-6
chromium⁽⁰⁾ hexacarbonyl

: 110015-89-9,110026-54-5
((CO)3Cr)2(C₆H₅CH₂)4C₄B₈H₈

: 110026-54-5,110015-89-9
((CO)3Cr)2(C₆H₅CH₂)4C₄B₈H₈

Guidance literature:: In tetrahydrofuran; dibutyl ether; a mixt. of the carborane, Cr(CO)6, anhyd. Bu2O and THF was refluxed under dry N2 for 18 h; cooled to room temp., solvent was removed in vacuo, residue was dissolved in CH2Cl2 and chromd. on a SiO2 column (eluent CH2Cl2-hexane) to give an isomer mixt. which was sepd. by TLC on SiO2;

Reference yield: 16.0%

: (((CO)3Cr)(C₆H₅CH₂)2C₂B₄H₄)2FeH₂

: 110015-89-9,110026-54-5
((CO)3Cr)2(C₆H₅CH₂)4C₄B₈H₈

: 110026-54-5,110015-89-9
((CO)3Cr)2(C₆H₅CH₂)4C₄B₈H₈

Guidance literature:: With oxygen; In dichloromethane; a flask with Fe-complex (obtained in vacuo) was filled with N2 (1 atm), opened to air, contents were dissolved in CH2Cl2, O2 gas was bubbled through the soln. for 8 h; yields are given based on carborane η6-(CO)3CrC6H5CH2C2B4H6CH2Ph; soln. was filtered through a SiO2 pad, washed with CH2Cl2, filtrate was concd., chromd. on a SiO2 column (eluent CH2Cl2-hexane) to give the isomer mixt. that was sepd. by thin-layer chromy. on SiO2 (CH2Cl2-hexane);