N,N'N''-tris(4-(2-hydroxybenzylidenehydrazinecarbonyl)phenyl)benzene-1,3,5-tricarboxamide

Base Information

• Chemical Name: N,N'N''-tris(4-(2-hydroxybenzylidenehydrazinecarbonyl)phenyl)benzene-1,3,5-tricarboxamide
• CAS No.: 1384111-95-8
• Molecular Formula: C₅₁H₃₉N₉O₉
• Molecular Weight: 921.926
• Mol file: 1384111-95-8.mol

Synonyms:

Chemical Property of N,N'N''-tris(4-(2-hydroxybenzylidenehydrazinecarbonyl)phenyl)benzene-1,3,5-tricarboxamide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N'N''-tris(4-(2-hydroxybenzylidenehydrazinecarbonyl)phenyl)benzene-1,3,5-tricarboxamide

There total 2 articles about N,N'N''-tris(4-(2-hydroxybenzylidenehydrazinecarbonyl)phenyl)benzene-1,3,5-tricarboxamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4,4',4''-[1,3,5-benzenetriyltris(carbonylimino)]trisbenzoic acid methyl ester (404018-63-9) → N,N'N''-tris(4-(2-hydroxybenzylidenehydrazinecarbonyl)phenyl)benzene-1,3,5-tricarboxamide (1384111-95-8)

Guidance literature:

Multi-step reaction with 2 steps

1: hydrazine hydrate / ethanol / 120 h

2: methanol / 12 h

With hydrazine hydrate; In methanol; ethanol;

DOI:10.1039/c2cc30497j

Reference yield:

N,N',N''-tris(4-(hydrazinecarbonyl)phenyl)benzene-1,3,5-tricarboxamide (1384111-93-6) + salicylaldehyde (90-02-8) → N,N'N''-tris(4-(2-hydroxybenzylidenehydrazinecarbonyl)phenyl)benzene-1,3,5-tricarboxamide (1384111-95-8)

Guidance literature:

In methanol; for 12h;

DOI:10.1039/c2cc30497j

Reference yield: 65.0%

cerium(III) nitrate hexahydrate + N,N'N''-tris(4-(2-hydroxybenzylidenehydrazinecarbonyl)phenyl)benzene-1,3,5-tricarboxamide (1384111-95-8) → Ce(III)4(N,N',N''-tris(4-(2-hydroxybenzylidene)hydrazinecarbonyl)phenyl)benzene-1,3,5-tricarboxamide

Guidance literature:

With NaOAc; In methanol; N,N-dimethyl-formamide; diffusion of MeOH into DMF soln. of C51H39N9O9 and Ce salt in presence of NaOAc; detd. by mass-spectrometry, XRD;

DOI:10.1039/c2cc30497j

upstream raw materials:

4,4',4''-[1,3,5-benzenetriyltris(carbonylimino)]trisbenzoic acid methyl ester

N,N',N''-tris(4-(hydrazinecarbonyl)phenyl)benzene-1,3,5-tricarboxamide

salicylaldehyde