KH₁₄₆-1

Base Information

• Chemical Name: KH₁₄₆-1
• CAS No.: 1391594-70-9
• Molecular Formula: C₅₈H₅₄O₁₀
• Molecular Weight: 911.061
• Mol file: 1391594-70-9.mol

Synonyms:

Chemical Property of KH₁₄₆-1

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of KH₁₄₆-1

There total 1 articles about KH₁₄₆-1 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

1,3-bis(10-bromoanthracen-9-yl)-4,6-bis(2-methoxyethoxy)benzene (1314555-39-9) + 1-bromo-3-methoxy-5-(methoxymethoxy)benzene (1391594-69-6) + zinc(II) chloride (7646-85-7,24359-56-6) → KH146-1 (1391594-70-9)

Guidance literature:

1-bromo-3-methoxy-5-(methoxymethoxy)benzene; With n-butyllithium; In tetrahydrofuran; hexane; at -80 ℃; for 2h; Inert atmosphere;

zinc(II) chloride; In tetrahydrofuran; hexane; at -80 - 20 ℃; for 4h; Inert atmosphere;

1,3-bis(10-bromoanthracen-9-yl)-4,6-bis(2-methoxyethoxy)benzene; With bis(benzonitrile)palladium(II) dichloride; tri-tert-butyl phosphine; In tetrahydrofuran; hexane; at 80 ℃; for 4h; Inert atmosphere;

DOI:10.1039/c2cc31383a

Reference yield:

KH146-1 (1391594-70-9) → C54H46O8

Guidance literature:

With hydrogenchloride; water; In tetrahydrofuran; methanol; at 20 ℃; for 24h;

DOI:10.1039/c2cc31383a

Reference yield:

KH146-1 (1391594-70-9) → KH146-2 (1391594-71-0)

Guidance literature:

Multi-step reaction with 2 steps

1: hydrogenchloride; water / tetrahydrofuran; methanol / 24 h / 20 °C

2: pyridine / 24.5 h / 0 - 20 °C

With pyridine; hydrogenchloride; water; In tetrahydrofuran; methanol;

DOI:10.1039/c2cc31383a

upstream raw materials:

1,3-bis(10-bromoanthracen-9-yl)-4,6-bis(2-methoxyethoxy)benzene

1-bromo-3-methoxy-5-(methoxymethoxy)benzene

zinc(II) chloride

Downstream raw materials:

KH₁₄₆-2